ArticleChemical science2015
Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system.
Article in Chemical science, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Stereospecific Epoxide-to-Cyclopropylamine Conversion by a Homologous Horner-Wadsworth-Emmons-Type Reaction With an Imine-Substituted Phosphine Oxide.Angewandte Chemie (International ed. in English) · 2026Article
- Intermolecular Enantioselective Nickel-Catalyzed Arylation of Un-Activated C(spAngewandte Chemie (International ed. in English) · 2026Article
- Access to chiral dihydrophenanthridinesChemical science · 2024Article
- Metal-catalysed C-C bond formation at cyclopropanes.Nature reviews. Chemistry · 2023Review
- Synthesis, In Silico and In Vivo Toxicity Assessment of Functionalized Pyridophenanthridinones via Sequential MW-Assisted Intramolecular Friedel-Crafts Alkylation and Direct C-H Arylation.Molecules (Basel, Switzerland) · 2022Article
- Cyclopropane-FusedJournal of the American Chemical Society · 2022Article
- Pd(II)-Catalyzed Enantioselective C(spJournal of the American Chemical Society · 2022Article
- Site-selective functionalization of remote aliphatic C-H bondsChemical science · 2020Review
- Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes.ACS catalysis · 2020Article
- Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future.Organometallics · 2019Article
- Palladium-Catalyzed Transformations of Alkyl C-H Bonds.Chemical reviews · 2017Article
- Palladium(0)-catalyzed asymmetric C(spChemical science · 2017Article
- Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenesChemical science · 2017Article
- Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds.Angewandte Chemie (International ed. in English) · 2016Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Taddol-based phosphoramidite ligands enable enantioselective palladium(0)-catalyzed C-H arylation of cyclopropanes. The cyclized products are obtained in high yields and enantioselectivities. The reported method provides efficient access to a broad range of synthetically attractive cyclopropyl containing dihydroquinolones and dihydroisoquinolones as well as allows for an efficient enantioselective construction of the 7-membered ring of the cyclopropyl indolobenzazepine core of BMS-791325.
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Registered trials
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