ArticleChemical communications (Cambridge, England)2017
Recent developments in transition-metal photoredox-catalysed reactions of carbonyl derivatives.
Article in Chemical communications (Cambridge, England), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
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Who cites it
34 citing papers in PubMed.
- Virtual Ligand-Assisted Screening for the Generation of Ketyl Radicals from Alkyl Ketones via Photoexcited Palladium Catalysis.Journal of the American Chemical Society · 2025Article
- Photoredox/Nickel-Catalyzed Diastereoselective Allylation of Aldehydes with Morita-Baylis-Hillman Adducts.ACS catalysis · 2025Article
- A Mild and Chemoselective Photoredox-Catalyzed Reduction of Aromatic Ketones.Tetrahedron letters · 2024Article
- Catalytic Aldehyde-Alkyne Couplings Triggered by Ketyl Radicals.Organic letters · 2024Article
- Aldehyde-Olefin Couplings Via Sulfoxylate-Mediated Oxidative Generation of Ketyl Radical Anions.Journal of the American Chemical Society · 2024Article
- Multielectron Reduction of Esters by a Diazabenzacenaphthenium Photoredox Catalyst.Journal of the American Chemical Society · 2024Article
- Tunable C-H functionalization and dearomatization enabled by an organic photocatalyst.Chemical science · 2024Article
- Reductive photoredox transformations of carbonyl derivatives enabled by strongly reducing photosensitizers.Chemical science · 2023Article
- Light-Induced Access to Carbazole-1,3-dicarbonitrile: A Thermally Activated Delayed Fluorescent (TADF) Photocatalyst for Cobalt-Mediated Allylations.The Journal of organic chemistry · 2023Article
- Excited-State Copper-Catalyzed [4 + 1] Annulation Reaction Enables Modular Synthesis of α,β-Unsaturated-γ-Lactams.Journal of the American Chemical Society · 2022Article
- Catalytic defluorinative ketyl-olefin coupling by halogen-atom transfer.Chemical science · 2022Article
- Diastereoselective and enantioselective photoredox pinacol coupling promoted by titanium complexes with a red-absorbing organic dye.Chemical science · 2022Article
- Article
- Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.Chemical reviews · 2022Review
- Switchable, Reagent-Controlled Diastereodivergent Photocatalytic Carbocyclisation of Imine-Derived α-Amino Radicals.Angewandte Chemie (International ed. in English) · 2021Article
- Catalytic Generation of Carbanions through Carbonyl Umpolung.Angewandte Chemie (International ed. in English) · 2021Review
- Photostable Ruthenium(II) Isocyanoborato Luminophores and Their Use in Energy Transfer and Photoredox Catalysis.JACS Au · 2021Article
- Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CONature communications · 2021Article
- Photoredox Propargylation of Aldehydes Catalytic in Titanium.The Journal of organic chemistry · 2021Article
- Isotope Effects and the Mechanism of Photoredox-Promoted [2 + 2] Cycloadditions of Enones.The Journal of organic chemistry · 2021Article
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Abstract
Single-electron reduction of C[double bond, length as m-dash]O and C[double bond, length as m-dash]N bonds of aldehydes, ketones, and imines results in the formation of ketyl and α-aminoalkyl anion radicals, respectively. These reactive intermediates are characterized by an altered electronic character with respect to their parent molecules and undergo a diverse range of synthetically useful transformations, which are not available to even-electron species. This Review summarizes the reactions of ketyl and α-aminyl radicals generated from carbonyl derivatives under transition-metal photoredox-catalysed conditions. We primarily focus on recent developments in the field, as well as give a brief overview of catalytic enantioselective transformations that provide a means to achieve precise stereocontrol over the reactivity of ion radicals.
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Registered trials
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