Evidence map›Paper›PMID 29114978›Full record

ArticleAngewandte Chemie (International ed. in English)2018

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C-C and C-H Bond Cleavage Cascades.

Elizabeth M Dauncey, Sara P Morcillo, James J Douglas, Nadeem S Sheikh, Daniele Leonori

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 58 papers.

0numbers the graph read from it
0cells of the map it votes in
58citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

58 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Radical Polarity.Journal of the American Chemical Society · 2024
    Article
  8. Article
  9. Article
  10. Copper-catalyzed generation of nitrogen-centered radicals and reactions thereof.ARKIVOC : free online journal of organic chemistry · 2024
    Article
  11. Article
  12. Iminologous epoxide ring-closure.Chemical science · 2022
    Article
  13. PdACS catalysis · 2022
    Article
  14. Photo-Induced Ruthenium-Catalyzed Double Remote C(spAngewandte Chemie (International ed. in English) · 2022
    Article
  15. Article
  16. Article
  17. Article
  18. Photocatalytic C(spChemical science · 2022
    Review
  19. Article
  20. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Elizabeth M DaunceySchool of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Sara P MorcilloSchool of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
James J DouglasEarly Chemical Development, Pharmaceutical Sciences, IMED Biotech Unit, AstraZeneca, Macclesfield, SK10 2NA, UK.
Nadeem S SheikhDepartment of Chemistry, Faculty of Science, King Faisal University, P.O. Box 380, Al-Ahsa, 31982, Saudi Arabia.
Daniele LeonoriSchool of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK.ORCID 0000-0002-7692-4504

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A photoinduced cascade strategy leading to a variety of differentially functionalised nitriles and ketones has been developed. These reactions rely on the oxidative generation of iminyl radicals from simple oximes. Radical transposition by C(sp

Indexed as

azidationcascade reactionschlorinationfluorinationphotoredox catalysis

Identifiers

PMID29114978
PMCPMC5814920

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.