ArticleAngewandte Chemie (International ed. in English)2017
A Versatile Route to Unstable Diazo Compounds via Oxadiazolines and their Use in Aryl-Alkyl Cross-Coupling Reactions.
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed.
- Geminal Difunctionalization of Ketones via C─S Bond Insertion of Photogenerated Donor-Donor Diazo Compounds.Angewandte Chemie (International ed. in English) · 2026Article
- Carbonyl-to-sulfur swap enabled by sequential double carbon-carbon bond activation.Science (New York, N.Y.) · 2025Article
- Synthesis of 3,3-Disubstituted Thietane Dioxides.The Journal of organic chemistry · 2024Article
- Visible Light-Induced Reactions of Diazo Compounds and Their Precursors.Chemical reviews · 2024Review
- Mechanism of Asymmetric Homologation of Alkenylboronic Acids with CFThe Journal of organic chemistry · 2024Article
- Synthesis of substituted benzylboronates by light promoted homologation of boronic acids withChemical science · 2023Article
- Deaminative coupling of benzylamines and arylboronic acids.Chemical science · 2023Article
- Photo-Induced Homologation of Carbonyl Compounds for Iterative Syntheses.Angewandte Chemie (International ed. in English) · 2022Article
- In-situ Kinetic Studies of Rh(II)-Catalyzed C-H Functionalization to Achieve High Catalyst Turnover Numbers.ACS catalysis · 2022Article
- Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.Chemical reviews · 2022Review
- Construction of NH-Unprotected Spiropyrrolidines and Spiroisoindolines by [4+1] Cyclizations of γ-Azidoboronic Acids with Cyclic N-Sulfonylhydrazones.Angewandte Chemie (International ed. in English) · 2022Article
- Uncommon carbene insertion reactions.Chemical science · 2021Review
- Article
- Hydrogen-bond donor and acceptor cooperative catalysis strategy for cyclic dehydration of diols to access O-heterocycles.Science advances · 2021Article
- Passerini-type reaction of boronic acids enables α-hydroxyketones synthesis.Nature communications · 2021Article
- Flow Photochemistry as a Tool in Organic Synthesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Review
- Thermal Stability and Explosive Hazard Assessment of Diazo Compounds and Diazo Transfer Reagents.Organic process research & development · 2020Review
- Recent synthesis of thietanes.Beilstein journal of organic chemistry · 2020Review
- Article
- Non-stabilized diazoalkane synthesisChemical science · 2019Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Coupling of readily available boronic acids and diazo compounds has emerged recently as a powerful metal-free carbon-carbon bond forming method. However, the difficulty in forming the unstable diazo compound partner in a mild fashion has hitherto limited their general use and the scope of the transformation. Here, we report the application of oxadiazolines as precursors for the generation of an unstable family of diazo compounds using flow UV photolysis and their first use in divergent protodeboronative and oxidative C(sp
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