ArticleNature communications2017
Stable and ordered amide frameworks synthesised under reversible conditions which facilitate error checking.
Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
What it found
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The trial behind it
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Who cites it
23 citing papers in PubMed.
- Covalent Organic Frameworks in Smart Food Packaging: Advances, Challenges, and Future Prospects.Comprehensive reviews in food science and food safety · 2026Review
- Amine-linked heteroporous covalent organic framework for synergistic anti-infective therapy of post-traumatic osteomyelitis.Nature communications · 2026Article
- Amorphous-to-crystalline transformation: a mechanochemical pathway to imine-linked covalent organic frameworks.RSC mechanochemistry · 2026Article
- Two-dimensional p-π conjugated amide-linked polymeric photocatalysts with enhanced carrier separation.Nature communications · 2026Article
- On-liquid surface synthesis of diyne-linked two-dimensional polymer crystals.Nature communications · 2025Article
- Unveiling cellular communications through rapid pan-membrane-protein labeling.Nature communications · 2025Article
- General synthesis of covalent organic frameworks under ambient condition within minutes via microplasma electrochemistry approach.Nature communications · 2025Article
- Covalently Linked 2D-CoLangmuir : the ACS journal of surfaces and colloids · 2024Article
- Probing Defects in Covalent Organic Frameworks.ACS applied materials & interfaces · 2024Review
- Construction of 2D/0D Graphene Oxide/Copper(I) Oxide-Incorporated Titanium Dioxide Mixed-Dimensional Membranes with Ultrafast Water Transport and Enhanced Antifouling Properties.ACS applied materials & interfaces · 2023Article
- Recent Trends in the Design, Synthesis and Biomedical Applications of Covalent Organic Frameworks.Polymers · 2022Review
- Green hydrothermal synthesis yields perylenebisimide-SiOJournal of materials chemistry. A · 2022Article
- Structural Analysis of Molecular Materials Using the Pair Distribution Function.Chemical reviews · 2022Review
- Covalent organic frameworks as multifunctional materials for chemical detection.Chemical Society reviews · 2021Review
- Hydrothermal polymerization of porous aromatic polyimide networks and machine learning-assisted computational morphology evolution interpretation.Journal of materials chemistry. A · 2021Article
- Reticular design and crystal structure determination of covalent organic frameworks.Chemical science · 2021Review
- Green Hydrothermal Synthesis of Fluorescent 2,3-Diarylquinoxalines and Large-Scale Computational Comparison to Existing Alternatives.ChemSusChem · 2021Article
- Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles.Angewandte Chemie (International ed. in English) · 2020Article
- Optical Properties of Isolated and Covalent Organic Framework-Embedded Ruthenium Complexes.The journal of physical chemistry. A · 2019Article
- Opportunities of Covalent Organic Frameworks for Advanced Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2019Review
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
abstarctCovalent organic frameworks (COFs) are network polymers with long-range positional order whose properties can be tuned using the isoreticular chemistry approach. Making COFs from strong bonds is challenging because irreversible rapid formation of the network produces amorphous materials with locked-in disorder. Reversibility in bond formation is essential to generate ordered networks, as it allows the error-checking that permits the network to crystallise, and so candidate network-forming chemistries such as amide that are irreversible under conventional low temperature bond-forming conditions have been underexplored. Here we show that we can prepare two- and three-dimensional covalent amide frameworks (CAFs) by devitrification of amorphous polyamide network polymers using high-temperature and high-pressure reaction conditions. In this way we have accessed reversible amide bond formation that allows crystalline order to develop. This strategy permits the direct synthesis of practically irreversible ordered amide networks that are stable thermally and under both strong acidic and basic hydrolytic conditions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.