ArticleNature communications2017
Chiral transcription in self-assembled tetrahedral Eu
Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
What it found
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Who cites it
25 citing papers in PubMed.
- Circularly Polarized Luminescent and Melt-Processable Copper(I)-Organic Glasses Based on 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl.Angewandte Chemie (International ed. in English) · 2026Article
- Enhancing Circularly Polarized Luminescence of Tb(III) Complexes via Remote Substitutions on Pyridine-2,6-Dicarboxamide.Chemistry, an Asian journal · 2026Article
- Supramolecular Assembly of Chiral Lanthanide Triple-Decker Metallocyclophanes LnInorganic chemistry · 2025Article
- Inversion of Circularly Polarized Luminescence in the Left-Handed Chitosan-Templated Co-assemblies.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Enantiopure trigonal bipyramidal coordination cages templated by in situ self-organized DNature communications · 2024Article
- Ligand Chirality Transfer from Solution State to the Crystalline Self-Assemblies in Circularly Polarized Luminescence (CPL) Active Lanthanide Systems.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Hexanuclear LnChemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Intramolecular charge transfer enables highly-efficient X-ray luminescence in cluster scintillators.Nature communications · 2023Article
- Subtle Stereochemical Effects Influence Binding and Purification Abilities of an FeJournal of the American Chemical Society · 2023Article
- Article
- Tailored Supramolecular Cage for Efficient Bio-Labeling.International journal of molecular sciences · 2023Article
- Differentiable Formation of Chiroptical Lanthanide Heterometallic LnChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- CPL on/off control of an assembled system by water soluble macrocyclic chiral sources with planar chirality.Chemical science · 2022Article
- Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of MJournal of the American Chemical Society · 2022Article
- Sky Blue and Yellow Cluster Light-Emitting Diodes Based on Asymmetric CuResearch (Washington, D.C.) · 2022Article
- Sorting Phenomena and Chirality Transfer in Fluoride-Bridged Macrocyclic Rare Earth Complexes.Inorganic chemistry · 2021Article
- Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length.Communications chemistry · 2021Article
- Helix-mediated over 1 nm-range chirality recognition by ligand-to-ligand interactions of dinuclear helicates.Chemical science · 2021Article
- Ancillary ligand modulated stereoselective self-assembly of triple-stranded Eu(iii) helicate featuring circularly polarized luminescence.RSC advances · 2021Article
- Unusual Magnetic Field Responsive Circularly Polarized Luminescence Probes with Highly Emissive Chiral Europium(III) Complexes.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
14 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Predictable stereoselective formation of supramolecular assembly is generally believed to be an important but complicated process. Here, we show that point chirality of a ligand decisively influences its supramolecular assembly behavior. We designed three closely related chiral ligands with different point chiralities, and observe their self-assembly into europium (Eu) tetrametallic tetrahedral cages. One ligand exhibits a highly diastereoselective assembly into homochiral (either ΔΔΔΔ or ΛΛΛΛ) Eu tetrahedral cages whereas the two other ligands, with two different approaches of loosened point chirality, lead to a significant breakdown of the diastereoselectivity to generate a mixture of (ΔΔΔΔ and ΛΛΛΛ) isomers. The cages are highly emissive (luminescence quantum yields of 16(1) to 18(1)%) and exhibit impressive circularly polarized luminescence properties (|g
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