ArticleJournal of the American Chemical Society2017
Synthesis of (+)-Pancratistatins via Catalytic Desymmetrization of Benzene.
Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed.
- An organometallic approach to the synthesis of heteropolycyclic compounds from benzenes.Nature communications · 2025Article
- Reimagining Dearomatization: Arenophile-Mediated Single-Atom Insertions and π-Extensions.Accounts of chemical research · 2025Article
- Phosphite mediated molecular editingChemical science · 2025Article
- Copper-Catalyzed DearomativeACS catalysis · 2024Article
- DearomativeJournal of the American Chemical Society · 2024Article
- Rejuvenation of dearomative cycloaddition reactionsChemical science · 2023Review
- Dearomative logic in natural product total synthesis.Natural product reports · 2022Review
- Intermolecular dearomative [4 + 2] cycloaddition of naphthalenesChemical science · 2022Article
- Amaryllidaceae Alkaloids Decrease the Proliferation, Invasion, and Secretion of Clinically Relevant Cytokines by Cultured Human Colon Cancer Cells.Biomolecules · 2022Article
- Conversion of Natural Narciclasine to Its C-1 and C-6 Derivatives and Their Antitumor Activity Evaluation: Some Unusual Chemistry of Narciclasine.Molecules (Basel, Switzerland) · 2022Article
- Electrophilic Aminating Agents in Total Synthesis.Angewandte Chemie (International ed. in English) · 2021Review
- Organocatalytic enantioselective dearomatization of thiophenes by 1,10-conjugate addition of indole imine methides.Nature communications · 2021Article
- Recent Visible Light and Metal Free Strategies in [2+2] and [4+2] Photocycloadditions.European journal of organic chemistry · 2021Review
- Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis.Chemical reviews · 2021Article
- Advances in Catalytic Asymmetric Dearomatization.ACS central science · 2021Review
- Development of a Scalable and Sublimation-Free Route to MTAD.Organic process research & development · 2020Article
- Lewis Acid Promoted Dearomatization of Naphthols.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization.Chem · 2020Article
- Cobalt-catalyzed aminocarbonylation of (hetero)aryl halides promoted by visible light.Chemical science · 2020Article
- Arene dearomatization through a catalytic N-centered radical cascade reaction.Nature communications · 2020Article
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Authors and funding
5 authors.
Funding
Abstract
A concise synthesis of (+)-pancratistatin and (+)-7-deoxypancratistatin from benzene using an enantioselective, dearomative carboamination strategy has been achieved. This approach, in combination with the judicious choice of subsequent olefin-type difunctionalization reactions, permits rapid and controlled access to a hexasubstituted core. Finally, minimal use of intermediary steps as well as direct, late stage C-7 hydroxylation provides both natural products in six and seven operations.
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