ArticleNature communications2017
Plasmonic tunnel junctions for single-molecule redox chemistry.
Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 30 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
30 citing papers in PubMed, 143 citations in OpenAlex.
- Extreme Polaritonic Interactions in a Room-Temperature Designable Sub-Nanocavity Quantum Electrodynamic Platform.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Plasmonic Enhancement of Fluorescence and Protein Dynamics in Living Mammalian Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- The Electric Field Morphology of Plasmonic Picocavities.Nano letters · 2025Article
- Electronically Perturbed Vibrational Excitations of the Luminescing Stable Blatter Radical.ACS nano · 2025Article
- Nanoplasmonic biosensors for environmental sustainability and human health.Chemical Society reviews · 2024Review
- DC vs AC Electrokinetics-Driven Nanoplasmonic Raman Monitoring of Charged Analyte Molecules in Ionic Solutions.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Development and mechanisms of photo-induced molecule junction device.Nanophotonics (Berlin, Germany) · 2024Review
- Understanding Polaritonic Chemistry from Ab Initio Quantum Electrodynamics.Chemical reviews · 2023Review
- Promises of Plasmonic Antenna-Reactor Systems in Gas-Phase COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Review
- Direct Bottom-UpChemical reviews · 2023Review
- Tracking water dimers in ambient nanocapsules by vibrational spectroscopy.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Molecular states and spin crossover of hemin studied by DNA origami enabled single-molecule surface-enhanced Raman scattering.Nanoscale · 2022Article
- Nanoparticle contact printing with interfacial engineering for deterministic integration into functional structures.Science advances · 2022Article
- Plasmonic phenomena in molecular junctions: principles and applications.Nature reviews. Chemistry · 2022Review
- Picocavities: a Primer.Nano letters · 2022Article
- Single-Molecule Surface-Enhanced Raman Spectroscopy.Sensors (Basel, Switzerland) · 2022Review
- Experimental characterization techniques for plasmon-assisted chemistry.Nature reviews. Chemistry · 2022Review
- Light-Driven Charge Transport and Optical Sensing in Molecular Junctions.Nanomaterials (Basel, Switzerland) · 2022Review
- Locating Single-Atom Optical Picocavities Using Wavelength-Multiplexed Raman Scattering.ACS photonics · 2021Article
- Tracking interfacial single-molecule pH and binding dynamics via vibrational spectroscopy.Science advances · 2021Article
Corrections and comments
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Authors and funding
12 authors at 3 institutions in 2 countries.
Funding
Abstract
Nanoparticles attached just above a flat metallic surface can trap optical fields in the nanoscale gap. This enables local spectroscopy of a few molecules within each coupled plasmonic hotspot, with near thousand-fold enhancement of the incident fields. As a result of non-radiative relaxation pathways, the plasmons in such sub-nanometre cavities generate hot charge carriers, which can catalyse chemical reactions or induce redox processes in molecules located within the plasmonic hotspots. Here, surface-enhanced Raman spectroscopy allows us to track these hot-electron-induced chemical reduction processes in a series of different aromatic molecules. We demonstrate that by increasing the tunnelling barrier height and the dephasing strength, a transition from coherent to hopping electron transport occurs, enabling observation of redox processes in real time at the single-molecule level.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.