ArticleMacromolecules2017
Wavelength-Selective Sequential Polymer Network Formation Controlled with a Two-Color Responsive Initiation System.
Article in Macromolecules, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
17 citing papers in PubMed, 76 citations in OpenAlex.
- Digital light processing bioprinting: bioink innovations and applications in tissue and organ regeneration.Journal of biological engineering · 2026Review
- Mixed-Functionalized Acylgermanes Result in Wavelength-Controlled Fragmentation.Angewandte Chemie (International ed. in English) · 2026Article
- Spatial control of curing kinetics in thiol-ene-systems through antagonistic photoreactions.Nature communications · 2025Article
- One-Vat Multimaterial 3D Printing: The Devil is in the Details.ACS central science · 2025Review
- Photobase-Catalyzed Thiol-ene Click Chemistry for Light-Based Additive Manufacturing.Polymer chemistry · 2025Article
- Fluorescence-readout as a powerful macromolecular characterisation tool.Chemical science · 2023Review
- A Review of Multi-Material 3D Printing of Functional Materials via Vat Photopolymerization.Polymers · 2022Review
- Continuous Additive Manufacturing using Olefin Metathesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Sequence-independent activation of photocycloadditions using two colours of light.Chemical science · 2022Article
- Determining Michael Acceptor Reactivity from Kinetic, Mechanistic, and Computational Analysis for the Base-catalyzed Thiol-Michael Reaction.Polymer chemistry · 2021Article
- Wavelength-Selective Photopolymerization of Hybrid Acrylate-Oxetane Liquid Crystals.Angewandte Chemie (International ed. in English) · 2021Article
- Expanding the Thiol-X Toolbox: Photoinitiation and Materials Application of the Acid-Catalyzed Thiol-ene (ACT) Reaction.Polymer chemistry · 2021Article
- Combining Photodeprotection and Ligation into a Dual-Color Gated Reaction System.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Rapid High-Resolution Visible Light 3D Printing.ACS central science · 2020Article
- Tunable Mechanical Anisotropy, Crack Guiding, and Toughness Enhancement in Two-Stage Reactive Polymer Networks.Advanced engineering materials · 2019Article
- Modeling the Optimal Conditions for Improved Efficacy and Crosslink Depth of Photo-Initiated Polymerization.Polymers · 2019Article
- Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
Abstract
We report a wavelength-selective polymerization process controlled by visible/UV light, whereby a base is generated for anion-mediated thiol-Michael polymerization reaction upon exposure at one wavelength (400-500 nm), while radicals are subsequently generated for a second stage radical polymerization at a second, independent wavelength (365 nm). Dual wavelength, light controlled sequential polymerization not only provides a relatively soft intermediate polymer that facilitates optimum processing and modification under visible light exposure but also enables a highly cross-linked, rigid final material after the UV-induced second stage radical polymerization. A photobase generator, NPPOC-TMG, and a photo-radical initiator, Irgacure 2959, were selected as the appropriate initiator pair for sequential thiol-Michael polymerization and acrylate homopolymerization. FT-IR and rheological tests were utilized to monitor the dual cure photo-polymerization process, and mechanical performance of the polymer was characterized at each distinct stage by dynamic mechanical analysis (DMA). By demonstrating complete light control in another sequential polymerization system (thiol-Michael and thiol-ene hybrid polymerization), this initiator pair exhibits great potential to regulate many other coupled anion and radical hybrid polymerizations in both a sequential and controllable manner.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.