Evidence map›Paper›PMID 29038513›Full record

ArticleNature communications2017

Anomalous Kondo resonance mediated by semiconducting graphene nanoribbons in a molecular heterostructure.

Yang Li, Anh T Ngo, Andrew DiLullo, Kyaw Zin Latt, Heath Kersell, Brandon Fisher, Peter Zapol, Sergio E Ulloa, Saw-Wai Hla

Abstract read
In one paragraph

Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Review
  2. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Yang LiCenter for Nanoscale Materials, Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, 60439, USA.
Anh T NgoMaterials Science Division, Argonne National Laboratory, Lemont, IL, 60439, USA.
Andrew DiLulloCenter for Nanoscale Materials, Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, 60439, USA.
Kyaw Zin LattCenter for Nanoscale Materials, Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, 60439, USA.
Heath KersellCenter for Nanoscale Materials, Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, 60439, USA.
Brandon FisherCenter for Nanoscale Materials, Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, 60439, USA.
Peter ZapolMaterials Science Division, Argonne National Laboratory, Lemont, IL, 60439, USA.ORCID http://orcid.org/0000-0003-0570-9169
Sergio E UlloaDepartment of Physics and Astronomy, Nanoscale and Quantum Phenomena Institute, Ohio University, Athens, OH, 45701, USA.ORCID http://orcid.org/0000-0002-3091-4984
Saw-Wai HlaCenter for Nanoscale Materials, Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, 60439, USA. hla@ohio.edu.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Kondo resonances in heterostructures formed by magnetic molecules on a metal require free host electrons to interact with the molecular spin and create delicate many-body states. Unlike graphene, semiconducting graphene nanoribbons do not have free electrons due to their large bandgaps, and thus they should electronically decouple molecules from the metal substrate. Here, we observe unusually well-defined Kondo resonances in magnetic molecules separated from a gold surface by graphene nanoribbons in vertically stacked heterostructures. Surprisingly, the strengths of Kondo resonances for the molecules on graphene nanoribbons appear nearly identical to those directly adsorbed on the top, bridge and threefold hollow sites of Au(111). This unexpectedly strong spin-coupling effect is further confirmed by density functional calculations that reveal no spin-electron interactions at this molecule-gold substrate separation if the graphene nanoribbons are absent. Our findings suggest graphene nanoribbons mediate effective spin coupling, opening a way for potential applications in spintronics.Semiconducting graphene nanoribbon provides a platform for band-gap engineering desired for electronic and optoelectronic applications. Here, Li et al. show that graphene nanoribbon can effectively mediate the interaction of molecular magnetic moment and electronic spin in underlying metallic substrates.

Identifiers

PMID29038513
PMCPMC5643342

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.