ArticleNature reviews. Chemistry2017
Well-defined nickel and palladium precatalysts for cross-coupling.
Article in Nature reviews. Chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 102 papers.
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Who cites it
102 citing papers in PubMed.
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- CpCo-Benzoquinone Complexes: Convenient CpCo(I) PrecatalystsSynthesis and Reactivity.Organometallics · 2026Article
- Spin-State Dichotomy of On-Cycle Cobalt(II) Organometallics Informs Polar Cobalt(0/II) Versus Radical Cobalt(I/II/III) Cross-Coupling Mechanisms.Angewandte Chemie (International ed. in English) · 2026Article
- A New Metal-Ester Bonding Motif for the Synthesis of Hybrid Molecular Catalysts on Metal Oxide Supports Leads to Tunable Reactivity.Angewandte Chemie (International ed. in English) · 2026Article
- Unlocking Catalyst Activation as a Critical Bottleneck in Cross-Coupling Reactions: Room-Temperature Couplings of Weak Nucleophiles Enabled by [Pd(1-MeNAP)TFA]Angewandte Chemie (International ed. in English) · 2026Article
- Iron Catalyzed Aryl-Aryl Kumada Cross-Coupling: A Mechanistic and Computational Investigation.Angewandte Chemie (International ed. in English) · 2026Article
- Deprotonation-controlled copper-free Pd-catalyzed Sonogashira couplingRSC advances · 2026Article
- Advances in NiACS catalysis · 2026Review
- Recent Advancements in Nickel-Catalyzed Electrochemical Reductive Cross-Coupling.ACS organic & inorganic Au · 2025Review
- Sequential one-potChemical science · 2025Article
- Catalyst-controlled stereodivergent synthesis of polysubstituted alkenes.Nature communications · 2025Article
- Iron(III)-Mediated C-H Alkylation: One-Electron Differentiation Increases Activity and Chemoselectivity.Journal of the American Chemical Society · 2025Article
- Combined X-Ray Emission Spectroscopy at Phosphorus and Nickel: Detecting Subtle Changes in Catalyst Electronic Structure at High Resolution.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- 2-Substituted vs 2,9-Disubstituted Phenanthroline-NiInorganic chemistry · 2025Article
- BidirectionalMacromolecules · 2025Article
- "Naked Nickel"-Catalyzed Heteroaryl-Heteroaryl Suzuki-Miyaura Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- Mechanochemical Sequential Deoxygenative Cross-Coupling Reactions of Phenols Under Ruthenium-Nickel Catalysis.Molecules (Basel, Switzerland) · 2025Article
- Ni/PiNe Heterogeneous Catalyst from Biomass Waste: Low-Loading, Ligand-Free Suzuki-Miyaura Cross-Coupling.ChemSusChem · 2025Article
- Easily Accessible and Solution-Stable Ni(0) Precatalysts for High-Throughput Experimentation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Bimetallic Nickel-Palladium Nanoparticles Supported on Multiwalled Carbon Nanotubes for Suzuki Cross-Coupling Reactions in Continuous Flow.Industrial & engineering chemistry research · 2025Article
42 more citing papers are in PubMed but not listed here.
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Authors and funding
3 authors.
Funding
Abstract
Transition metal-catalysed cross-coupling is one of the most powerful synthetic methods and has led to vast improvements in the synthesis of pharmaceuticals, agrochemicals and precursors for materials chemistry. A major advance in cross-coupling over the past 20 years is the utilization of well-defined, bench-stable Pd and Ni precatalysts that do not require the addition of free ancillary ligand, which can hinder catalysis by occupying open coordination sites on the metal. The development of precatalysts has resulted in new reactions and expanded substrate scopes, enabling transformations under milder conditions and with lower catalyst loadings. This Review highlights recent advances in the development of Pd and Ni precatalysts for cross-coupling, and provides a critical comparison between the state of the art in Pd- and Ni-based systems.
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