ArticleChemical science2017
X-ray circular dichroism signals: a unique probe of local molecular chirality.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Deconstructing Chirality: Probing Local and Nonlocal Effects in Azobenzene Derivatives with X-ray Circular Dichroism.The journal of physical chemistry letters · 2025Article
- Chiral light-matter interactions in solution-processable semiconductors.Nature reviews. Chemistry · 2025Review
- Time-Resolved Circular Dichroism in Molecules: Experimental and Theoretical Advances.Molecules (Basel, Switzerland) · 2024Review
- Time-resolved enantiomer-exchange probed by using the orbital angular momentum of X-ray light.Chemical science · 2023Article
- Element- and enantiomer-selective visualization of molecular motion in real-time.Nature communications · 2023Article
- Ultrafast chirality: the road to efficient chiral measurements.Physical chemistry chemical physics : PCCP · 2022Review
- Stabilization of an Enantiopure Sub-monolayer of Helicene Radical Cations on a Au(111) Surface through Noncovalent Interactions.Angewandte Chemie (International ed. in English) · 2021Article
- Real-time probing of chirality during a chemical reaction.Proceedings of the National Academy of Sciences of the United States of America · 2019Article
- X-ray Raman optical activity of chiral molecules.Chemical science · 2019Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Core-resonant circular dichroism (CD) signals are induced by molecular chirality and vanish for achiral molecules and racemic mixtures. The highly localized nature of core excitations makes them ideal probes of local chirality within molecules. Simulations of the circular dichroism spectra of several molecular families illustrate how these signals vary with the electronic coupling to substitution groups, the distance between the X-ray chromophore and the chiral center, geometry, and chemical structure. Clear insight into the molecular structure is obtained through analysis of the X-ray CD spectra.
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Registered trials
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