ArticleChemical science2017
Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical-radical coupling.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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Who cites it
20 citing papers in PubMed, 91 citations in OpenAlex.
- Chiral-at-metal catalysts: history, terminology, design, synthesis, and applications.Chemical Society reviews · 2025Review
- Harnessing the potential of acyl triazoles in bifunctional cobalt-catalyzed radical cross-coupling reactions.Nature communications · 2024Article
- Photoenzymatic Enantioselective Intermolecular Radical Hydroamination.Nature catalysis · 2023Article
- Metal Stereogenicity in Asymmetric Transition Metal Catalysis.Chemical reviews · 2023Review
- Access to chiral β-sulfonyl carbonyl compoundsChemical science · 2022Article
- Recent advances in visible light-induced C(Nature reviews. Chemistry · 2022Article
- Recent Development of Bis-Cyclometalated Chiral-at-Iridium and Rhodium Complexes for Asymmetric Catalysis.ACS organic & inorganic Au · 2022Review
- Investigation of the C-N Bond-Forming Step in a Photoinduced, Copper-Catalyzed Enantioconvergent N-Alkylation: Characterization and Application of a Stabilized Organic Radical as a Mechanistic Probe.Journal of the American Chemical Society · 2022Article
- Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.Chemical reviews · 2022Review
- Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis.Chemical reviews · 2022Review
- Enantioselective Hydroamination of Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer.Journal of the American Chemical Society · 2020Article
- A Selenourea-Thiourea Brønsted Acid Catalyst Facilitates Asymmetric Conjugate Additions of Amines to α,β-Unsaturated Esters.Journal of the American Chemical Society · 2020Article
- Electrochemical oxidation induced intermolecular aromatic C-H imidation.Nature communications · 2019Article
- Reductive Arylation of Arylidene Malonates Using Photoredox Catalysis.ACS catalysis · 2019Article
- Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents.Nature communications · 2019Article
- Catalytic enantioselective radical coupling of activated ketones withChemical science · 2018Article
- Recent developments in transition-metal photoredox-catalysed reactions of carbonyl derivatives.Chemical communications (Cambridge, England) · 2017Article
- Visible-Light-Activated Asymmetric β-C-H Functionalization of Acceptor-Substituted Ketones with 1,2-Dicarbonyl Compounds.Journal of the American Chemical Society · 2017Article
- Photoredox Imino Functionalizations of Olefins.Angewandte Chemie (International ed. in English) · 2017Article
- Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system.Chemical science · 2017Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A new mechanistic approach for the catalytic, enantioselective conjugate addition of nitrogen-based nucleophiles to acceptor-substituted alkenes is reported, which is based on a visible light induced and phosphate base promoted transfer of a single electron from a nitrogen nucleophile to a catalyst-bound acceptor-substituted alkene, followed by a stereocontrolled C-N bond formation through stereocontrolled radical-radical coupling. Specifically,
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.