ArticleJournal of molecular modeling2017
Surfactant chain length and concentration influence on the interfacial tension of two immiscible model liquids: a coarse-grained approach.
Article in Journal of molecular modeling, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 0 citations in OpenAlex.
- Measuring the Surface Tension of Atmospheric Particles and Relevant Mixtures to Better Understand Key Atmospheric Processes.Chemical reviews · 2024Review
- The Effect of Mixtures and Additives on Dissolving Surfactant Lamellar Phases.ACS physical chemistry Au · 2024Article
- Synthesis, surface activity, and corrosion inhibition capabilities of new non-ionic gemini surfactants.Scientific reports · 2024Article
- Effect of sequence distribution of block copolymers on the interfacial properties of ternary mixtures: a dissipative particle dynamics simulation.RSC advances · 2022Article
- DPD Study on the Interfacial Properties of PEO/PEO-PPO-PEO/PPO Ternary Blends: Effects of Pluronic Structure and Concentration.Polymers · 2021Article
- Effects of Repulsion Parameter and Chain Length of Homopolymers on Interfacial Properties of APolymers · 2021Article
- Dissipative Particle Dynamics Study on Interfacial Properties of Symmetric Ternary Polymeric Blends.Polymers · 2021Article
Corrections and comments
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Authors and funding
7 authors at 4 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The interfacial tension between immiscible liquids is studied as a function of a model linear surfactant length and concentration using coarse-grained, dissipative particle dynamics numerical simulations. The adsorption isotherms obtained from the simulations are found to be in agreement with Langmuir's model. The reduction of the interfacial tension with increasing surfactant concentration is found to display some common characteristics for all the values of chain length modeled, with our predictions being in agreement with Szyszkowski's equation. Lastly, the critical micelle concentration is predicted for all surfactant lengths, finding exponentially decaying behavior, in agreement with Kleven's model. It is argued that these findings can be helpful guiding tools in the interpretation of available experiments and in the design of new ones with new surfactants and polymers.
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