ArticleChemical science2017
Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Mechanistic Investigations of Cobalt-Catalyzed, Aminoquinoline-Directed C(spJournal of the American Chemical Society · 2025Article
- Enantioselective palladaelectro-catalyzed C-H olefinations and allylations for N-C axial chirality.Chemical science · 2021Article
- Ni-Catalyzed Regioselective 1,2-Dialkylation of Alkenes Enabled by the Formation of Two C(spJournal of the American Chemical Society · 2020Article
- Palladium-catalyzed direct asymmetric C-H bond functionalization enabled by the directing group strategy.Chemical science · 2020Review
- Cobalt-CatalyzedACS omega · 2020Article
- Palladium-catalyzed cross-coupling reaction of alkenyl aluminums with 2-bromobenzo[RSC advances · 2020Article
- Selective Dealkenylative Functionalization of Styrenes via C-C Bond Cleavage.Research (Washington, D.C.) · 2020Article
- Ligand-enabledChemical science · 2018Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Unactivated acyclic internal aliphatic olefins are often found to be unreactive in conventional alkenylation reactions. To address this problem, a cobalt catalyzed allylic selective dehydrogenative Heck reaction with internal aliphatic olefins has been developed. The method is highly regio- and stereoselective, the conditions are mild and a wide variety of functional groups can be tolerated. Remarkably, both internal and terminal aliphatic olefins can be employed, thereby significantly expanding the scope of alkenylation chemistry with aliphatic olefins.
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Registered trials
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