ArticleCoordination chemistry reviews2017
K- and L-edge X-ray Absorption Spectroscopy (XAS) and Resonant Inelastic X-ray Scattering (RIXS) Determination of Differential Orbital Covalency (DOC) of Transition Metal Sites.
Article in Coordination chemistry reviews, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 75 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
75 citing papers in PubMed.
- Understanding the Electronic Structure of Ruthenium Oxides during Redox Cycling with High Energy Resolution X-ray Absorption Spectroscopy.The journal of physical chemistry letters · 2026Article
- Local Coordination Motif Compatibility Induces the Formation of Shortened Fe3+-O-Ni3+δ Moieties as Active Sites for Highly Efficient Oxygen Evolution Reaction.Journal of the American Chemical Society · 2026Article
- Bridging Transition Metal and Anion Redox Processes in Li-Rich Sulfide Cathodes.Chemistry of materials : a publication of the American Chemical Society · 2026Article
- Enzymatic X-ray absorption spectroelectrochemistry.Nature protocols · 2026Review
- Protein-Driven Copper Redox Regulation: Uncovering the Role of Disulphide Bonds and Allosteric Modulation.Angewandte Chemie (International ed. in English) · 2026Article
- Electronic Structure Contributions to the Reactivity of Mononuclear FeAccounts of chemical research · 2026Article
- Isolation of a Terminal Cobalt Nitride in a Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
- High energy resolution fluorescence detected X-ray absorption spectroscopy (HERFD-XAS) for studies of metals and metalloids in biology: current innovations and future perspectives.Metallomics : integrated biometal science · 2025Review
- Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Lowering the Cu-O bond energy in CuO nanocatalysts enhances the efficiency of NHNature communications · 2025Article
- Determining structure and Zn-specific Lewis acid-base descriptors for diorganozincs in non-coordinating solvents using X-ray spectroscopy.Communications chemistry · 2025Article
- Heterointercalation in Chevrel-Phase Sulfides: A Model Periodic Solid for the Investigation of Chain Electron Transfer.Journal of the American Chemical Society · 2025Article
- Single rhenium atoms on nanomagnetite: Probing the recharge process that controls the fate of rhenium in the environment.Science advances · 2025Article
- The OÆSE endstation at BESSY II: operando X-ray absorption spectroscopy for energy materials.Journal of synchrotron radiation · 2025Article
- Tuning the Electronic Properties of Tetravalent Cerium Complexes via Ligand Derivatization.Inorganic chemistry · 2025Article
- Tracking Active Site Formation during Oxidative Activation of Copper-Exchanged Zeolites for Methane-to-Methanol Conversion.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- High-Energy Density Li-Ion Battery Cathode Using Only Industrial Elements.Journal of the American Chemical Society · 2025Article
- Electronic Structures of Iron in Oxide Glasses via 1s3p Resonant Inelastic X-ray Scattering.The journal of physical chemistry letters · 2025Article
- Operando Characterization of Fe in Doped NiJournal of the American Chemical Society · 2025Article
- Multiconfigurational Electronic Structure of Nickel Cross-Coupling Catalysts Revealed by X-ray Absorption Spectroscopy.The journal of physical chemistry letters · 2025Article
15 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
Abstract
Continual advancements in the development of synchrotron radiation sources have resulted in X-ray based spectroscopic techniques capable of probing the electronic and structural properties of numerous systems. This review gives an overview of the application of metal K-edge and L-edge X-ray absorption spectroscopy (XAS), as well as K resonant inelastic X-ray scattering (RIXS), to the study of electronic structure in transition metal sites with emphasis on experimentally quantifying 3d orbital covalency. The specific sensitivities of K-edge XAS, L-edge XAS, and RIXS are discussed emphasizing the complementary nature of the methods. L-edge XAS and RIXS are sensitive to mixing between 3d orbitals and ligand valence orbitals, and to the differential orbital covalency (DOC), that is, the difference in the covalencies for different symmetry sets of the d orbitals. Both L-edge XAS and RIXS are highly sensitive to and enable separation of and donor bonding and back bonding contributions to bonding. Applying ligand field multiplet simulations, including charge transfer via valence bond configuration interactions, DOC can be obtained for direct comparison with density functional theory calculations and to understand chemical trends. The application of RIXS as a probe of frontier molecular orbitals in a heme enzyme demonstrates the potential of this method for the study of metal sites in highly covalent coordination sites in bioinorganic chemistry.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.