Evidence map›Paper›PMID 28967754›Full record

ArticleLangmuir : the ACS journal of surfaces and colloids2017

UV and NIR-Responsive Layer-by-Layer Films Containing 6-Bromo-7-hydroxycoumarin Photolabile Groups.

Matthew J Feeney, Xiaoran Hu, Rati Srinivasan, Nhi Van, Martin Hunter, Irene Georgakoudi, Samuel W Thomas

Abstract read
In one paragraph

Article in Langmuir : the ACS journal of surfaces and colloids, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Matthew J FeeneyDepartment of Chemistry, 62 Talbot Avenue, Tufts University , Medford, Massachusetts 02155, United States.
Xiaoran HuDepartment of Chemistry, 62 Talbot Avenue, Tufts University , Medford, Massachusetts 02155, United States.ORCID 0000-0001-7598-4516
Rati SrinivasanDepartment of Chemistry, 62 Talbot Avenue, Tufts University , Medford, Massachusetts 02155, United States.
Nhi VanDepartment of Chemistry, 62 Talbot Avenue, Tufts University , Medford, Massachusetts 02155, United States.
Martin HunterDepartment of Biomedical Engineering, 4 Colby Street, Tufts University , Medford, Massachusetts 02155, United States.
Irene GeorgakoudiDepartment of Biomedical Engineering, 4 Colby Street, Tufts University , Medford, Massachusetts 02155, United States.
Samuel W ThomasDepartment of Chemistry, 62 Talbot Avenue, Tufts University , Medford, Massachusetts 02155, United States.ORCID 0000-0002-0811-9781

Funding

Acquisition of Leica confocal/multiphoton microscopeS10OD021624 · OD · TUFTS UNIVERSITY MEDFORD · PI GEORGAKOUDI, IRENE · 2016 to 2016
$600k
Singlet Oxygen Degradable Materials to Harness the Near-Infrared Biological Transparency Window EfficientlyR21EB022207 · NIBIB · TUFTS UNIVERSITY MEDFORD · PI THOMAS, SAMUEL W · 2016 to 2017
$376k
NIBIB NIH HHS R21 EB022207NIH HHS S10 OD021624
6 · The paper itself

Abstract

This paper describes polyelectrolyte multilayer films prepared by the layer-by-layer (LbL) technique capable of undergoing dissolution upon exposure to either ultraviolet or near-infrared light. Film dissolution is driven by photochemical deprotection of a random methacrylic copolymer with two types of side chains: (i) 6-bromo-7-hydroxycoumarinyl esters, photocleavable groups that are known to have substantial two-photon photolysis cross sections, and (ii) cationic residues from the commercially available monomer N,N-dimethylaminoethyl methacrylate (DMAEMA). In addition, the dependence of stability of both unirradiated and irradiated films on pH provides experimental evidence for the necessity of disrupting both ion-pairing and hydrophobic interactions between polyelectrolytes to realize film dissolution. This work therefore provides both new fundamental insight regarding photolabile LbL films and expands their applied capabilities to nonlinear photochemical processes.

Indexed as

Infrared RaysPhotonsPolymersUmbelliferonesPolymersUmbelliferones

Identifiers

PMID28967754
PMCPMC5647567

What OpenQuestion holds

Textmetadata
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.