ArticleJournal of the American Chemical Society2017
Transition Metal Free C-N Bond Forming Dearomatizations and Aryl C-H Aminations by in Situ Release of a Hydroxylamine-Based Aminating Agent.
Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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Who cites it
17 citing papers in PubMed.
- Article
- Copper-Catalyzed Alkylative Deoxygenation ofMolecules (Basel, Switzerland) · 2026Article
- Article
- Reverse polarity of amide nitrogen enables expedient access to N-cyano amides.Nature communications · 2025Article
- Organocatalytic Electrophilic Arene Amination: Rapid Synthesis of 2-Quinolones.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Formal Dearomative Hydroamination of 2-Arylphenols.The Journal of organic chemistry · 2025Article
- Ground State Generation and Cyclization of Aminium Radicals in the Formation of Tetrahydroquinolines.Organic letters · 2024Article
- Article
- Copper-catalyzed [1,3]-nitrogen rearrangement ofChemical science · 2023Article
- The advent of electrophilic hydroxylamine-derived reagents for the direct preparation of unprotected amines.Chemical communications (Cambridge, England) · 2022Review
- An Aminative Rearrangement of O-(Arenesulfonyl)hydroxylamines: Facile Access to ortho-Sulfonyl Anilines.Angewandte Chemie (International ed. in English) · 2022Article
- Hydroxylamine-mediated C-C amination via an aza-hock rearrangement.Nature communications · 2021Article
- Electrophilic Aminating Agents in Total Synthesis.Angewandte Chemie (International ed. in English) · 2021Review
- Electrochemical Dehydrogenative C(spChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Generation and application of Cu-bound alkyl nitrenes for the catalyst-controlled synthesis of cyclic β-amino acids.Chemical science · 2021Article
- Palladium-Catalyzed Dearomative syn-1,4-Carboamination with Grignard Reagents.Angewandte Chemie (International ed. in English) · 2019Article
- Palladium-Catalyzed Dearomative syn-1,4-Diamination.Journal of the American Chemical Society · 2019Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
We outline a simple protocol that accesses directly unprotected secondary amines by intramolecular C-N bond forming dearomatization or aryl C-H amination. The method is dependent on the generation of a potent electrophilic aminating agent released by in situ deprotection of O-Ts activated N-Boc hydroxylamines.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.