Evidence map›Paper›PMID 28943668›Full record

ArticleTetrahedron letters2017

Acetone promoted 1,4-migration of an alkoxycarbonyl group on a syn-1,2-diamine.

Tanya Napolitano, Shu-Yuan Cheng, Brooke Nielsen, Christopher Choi, William Aguilar, Manuel M Paz, Anne-Marie Sapse, Elise Champeil

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Tetrahedron letters, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Tanya NapolitanoJohn Jay College of Criminal Justice, New York, 524 west 59 Street, New York, NY, 10019, USA.
Shu-Yuan ChengJohn Jay College of Criminal Justice, New York, 524 west 59 Street, New York, NY, 10019, USA.
Brooke NielsenJohn Jay College of Criminal Justice, New York, 524 west 59 Street, New York, NY, 10019, USA.
Christopher ChoiJohn Jay College of Criminal Justice, New York, 524 west 59 Street, New York, NY, 10019, USA.
William AguilarJohn Jay College of Criminal Justice, New York, 524 west 59 Street, New York, NY, 10019, USA.
Manuel M PazDepartamento de Química Orgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain.
Anne-Marie SapseJohn Jay College of Criminal Justice, New York, 524 west 59 Street, New York, NY, 10019, USA.
Elise ChampeilJohn Jay College of Criminal Justice, New York, 524 west 59 Street, New York, NY, 10019, USA.

Funding

Role of p21 signaling pathway in response to MC & DMC DNA Interstrand CrosslinksSC3GM105460 · NIGMS · JOHN JAY COLLEGE OF CRIMINAL JUSTICE · PI CHAMPEIL, ELISE · 2014 to 2022
$1.2M
NIGMS NIH HHS SC3 GM105460
6 · The paper itself

Abstract

A 2-protected cis-amino mitosene undergoes an irreversible acetone promoted isomerization and converts to the 1-isomer. Kinetic studies and DFT calculations of the reaction are reported. An organocatalytic mechanism is proposed, involving a covalent intermediate formed by reaction of the mitosene and acetone.

Indexed as

AcetoneAlkoxycarbonyl migrationMitoseneOrganocatalytic mechanism

Identifiers

PMID28943668
PMCPMC5604470

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.