Evidence map›Paper›PMID 28937664›Full record

ArticleNature chemistry2017

Transition-metal-free chemo- and regioselective vinylation of azaallyls.

Minyan Li, Osvaldo Gutierrez, Simon Berritt, Ana Pascual-Escudero, Ahmet Yeşilçimen, Xiaodong Yang, Javier Adrio, Georgia Huang, Eiko Nakamaru-Ogiso, Marisa C Kozlowski and 1 more

Abstract read
In one paragraph

Article in Nature chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.

0numbers the graph read from it
0cells of the map it votes in
31citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

31 citing papers in PubMed.

  1. Article
  2. α-C-H Functionalization of Benzylamines: A Crucial Yet Challenging Transformation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Review
  3. Article
  4. Review
  5. Article
  6. Article
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  10. Article
  11. Article
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  13. Article
  14. Article
  15. Article
  16. Article
  17. Article
  18. Transition-metal-free C(spChemical science · 2020
    Article
  19. Article
  20. 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines.Synlett : accounts and rapid communications in synthetic organic chemistry · 2019
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Minyan LiDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Osvaldo GutierrezDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Simon BerrittDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.ORCID 0000-0001-5572-6771
Ana Pascual-EscuderoDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Ahmet YeşilçimenDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Xiaodong YangDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Javier AdrioDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Georgia HuangDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Eiko Nakamaru-OgisoDepartment of Biochemistry and Biophysics, EPR Laboratory, University of Pennsylvania, 422 Curie Boulevard, Philadelphia, Pennsylvania 19104, USA.
Marisa C KozlowskiDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.
Patrick J WalshDepartment of Chemistry, Roy and Diana Vagelos Laboratories, Penn/Merck Laboratory for High-Throughput Experimentation, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA.ORCID 0000-0001-8392-4150

Funding

Computational Methods for Selective CatalysisR01GM087605 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI KOZLOWSKI, MARISA C · 2010 to 2019
$2.4M
Arylation of weakly acidic sp3 hybridized C-H'sR01GM104349 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI WALSH, PATRICK J · 2013 to 2016
$1.3M
NIGMS NIH HHS R01 GM087605NIGMS NIH HHS R01 GM104349
6 · The paper itself

Abstract

Direct C(sp

Indexed as

Allyl CompoundsAminesAza CompoundsMolecular StructureStereoisomerismTransition ElementsVinyl CompoundsAllyl CompoundsAminesAza CompoundsTransition ElementsVinyl Compounds

Identifiers

PMID28937664
PMCPMC5650226

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.