ArticleScience advances2017
Identifying key intermediates generated in situ from Cu(II) salt-catalyzed C-H functionalization of aromatic amines under illumination.
Article in Science advances, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 52 citations in OpenAlex.
- Modular synthesis of functionalized azetidines through visible-light copper-catalyzed carboamination of 1,3-dienes with azabicyclo[1.1.0]butanes.Chemical science · 2026Article
- Field Effects Govern the Decarboxylation of Copper(II)-Benzoates: Kinetic and Mechanistic Studies.Organometallics · 2026Article
- One-step electrochemical conversion of propane to acetone of 96% purity.Nature communications · 2025Article
- Recent Advances in Visible Light-Induced C-H Functionalization of Imidazo[1,2-a]pyridines.Molecules (Basel, Switzerland) · 2025Review
- Grignard Reagent Addition to Pyridinium Salts: A Catalytic Approach to Chiral 1,4-Dihydropyridines.ACS catalysis · 2024Article
- Visible Light-Induced Transition Metal Catalysis.Chemical reviews · 2022Review
- Visible-light-mediated copper photocatalysis for organic syntheses.Beilstein journal of organic chemistry · 2021Review
- Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study.Chemical science · 2020Article
- Enantioselective aerobic oxidative cross-dehydrogenative coupling of glycine derivatives with ketones and aldehydesChemical science · 2020Article
- Gold(I)-Catalyzed Aromatization: Expeditious Synthesis of Polyfunctionalized Naphthalenes.iScience · 2019Article
Corrections and comments
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Authors and funding
13 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Copper compounds involved in photocatalysis have recently spurred considerable interest for their novel transformations. However, mechanistic investigations are still in infancy. We find a new type of reaction, that is, Cu(II) salt-catalyzed C-H functionalization of aromatic amines triggered by visible light irradiation. An array of mechanistic observations, including high-resolution mass spectrometry, ultraviolet-visible absorption spectrum, electron spin resonance, x-ray absorption near-edge structure, and density functional theory calculation, have identified the key intermediates generated in situ in the transformation. Integration of single-electron transfer, singlet oxygen (
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Registered trials
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