ArticleProceedings of the National Academy of Sciences of the United States of America2017
Mesoscale martensitic transformation in single crystals of topological defects.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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11 citing papers in PubMed, 57 citations in OpenAlex.
- Direct simulation and machine learning structure identification unravel soft martensitic transformation and twinning dynamics.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Directed crystalline symmetry transformation of blue-phase liquid crystals by reverse electrostriction.Nature communications · 2024Article
- Functional soft materials from blue phase liquid crystals.Science advances · 2023Review
- Effect of Amorphous Crosslinker on Phase Behavior and Electro-Optic Response of Polymer-Stabilized Blue Phase Liquid Crystals.Nanomaterials (Basel, Switzerland) · 2021Article
- Diffusionless transformation of soft cubic superstructure from amorphous to simple cubic and body-centered cubic phases.Nature communications · 2021Article
- 3D Chiral Photonic Nanostructures Based on Blue-Phase Liquid Crystals.Small science · 2021Article
- Grain polydispersity and coherent crystal reorientations are features to foster stress hotspots in polycrystalline alloys under load.Science advances · 2021Article
- Prolate and oblate chiral liquid crystal spheroids.Science advances · 2020Article
- Soft crystal martensites: An in situ resonant soft x-ray scattering study of a liquid crystal martensitic transformation.Science advances · 2020Article
- Reconfiguration of three-dimensional liquid-crystalline photonic crystals by electrostriction.Nature materials · 2020Article
- Sculpted grain boundaries in soft crystals.Science advances · 2019Article
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Authors and funding
9 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Liquid-crystal blue phases (BPs) are highly ordered at two levels. Molecules exhibit orientational order at nanometer length scales, while chirality leads to ordered arrays of double-twisted cylinders over micrometer scales. Past studies of polycrystalline BPs were challenged by the existence of grain boundaries between randomly oriented crystalline nanodomains. Here, the nucleation of BPs is controlled with precision by relying on chemically nanopatterned surfaces, leading to macroscopic single-crystal BP specimens where the dynamics of mesocrystal formation can be directly observed. Theory and experiments show that transitions between two BPs having a different network structure proceed through local reorganization of the crystalline array, without diffusion of the double-twisted cylinders. In solid crystals, martensitic transformations between crystal structures involve the concerted motion of a few atoms, without diffusion. The transformation between BPs, where crystal features arise in the submicron regime, is found to be martensitic in nature when one considers the collective behavior of the double-twist cylinders. Single-crystal BPs are shown to offer fertile grounds for the study of directed crystal nucleation and the controlled growth of soft matter.
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