Evidence map›Paper›PMID 28858496›Full record

ArticleInorganic chemistry2017

Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand.

Wei-Min Ching, Ang Zhou, Johannes E M N Klein, Ruixi Fan, Gerald Knizia, Christopher J Cramer, Yisong Guo, Lawrence Que

Erratum issuedAbstract read
In one paragraph

Article in Inorganic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed.

  1. Article
  2. A Reactive, Photogenerated High-Spin (Journal of the American Chemical Society · 2021
    Article
  3. Article
  4. Article
  5. Article
  6. Dioxygen-Derived Nonheme Mononuclear FeJournal of the American Chemical Society · 2019
    Article
  7. Structural implications of the paramagnetically shifted NMR signals from pyridine H atoms on synthetic nonheme FeJournal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2019
    Article
  8. Article
  9. Article
  10. Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2018
    Article
  11. Mn K-edge X-ray absorption studies of mononuclear Mn(III)-hydroxo complexes.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2017
    Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

8 authors.

Ang Zhou
Ruixi FanDepartment of Chemistry, Carnegie Mellon University , Pittsburgh, Pennsylvania 15213, United States.
Gerald KniziaDepartment of Chemistry, Pennsylvania State University , 401A Chemistry Bldg; University Park, Pennsylvania 16802, United States.ORCID http://orcid.org/0000-0002-7163-4823
Yisong GuoDepartment of Chemistry, Carnegie Mellon University , Pittsburgh, Pennsylvania 15213, United States.ORCID http://orcid.org/0000-0002-4132-3565

Funding

X-ray Absorption Spectroscopy (XAS) pp.711-759P41GM103393 · NIGMS · STANFORD UNIVERSITY · PI HODGSON, KEITH O · 2012 to 2019
$30.6M
Synthetic Models and Spectroscopy of Nonheme Diiron EnzymesR01GM038767 · NIGMS · UNIVERSITY OF MINNESOTA TWIN CITIES · PI QUE, LAWRENCE · 1987 to 2018
$5.8M
NIGMS NIH HHS P41 GM103393NIGMS NIH HHS R01 GM038767
6 · The paper itself

Abstract

Nonheme mononuclear hydroxoiron(III) species are important intermediates in biological oxidations, but well-characterized examples of synthetic complexes are scarce due to their instability or tendency to form μ-oxodiiron(III) complexes, which are the thermodynamic sink for such chemistry. Herein, we report the successful stabilization and characterization of a mononuclear hydroxoiron(III) complex, [Fe

Identifiers

PMID28858496
PMCPMC8991986

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.