Evidence map›Paper›PMID 28855506›Full record

ArticleNature communications2017

Developing a molecular picture of soil organic matter-mineral interactions by quantifying organo-mineral binding.

C J Newcomb, N P Qafoku, J W Grate, V L Bailey, J J De Yoreo

Erratum issuedOpen access · goldAbstract read
In one paragraph

Article in Nature communications, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 33 papers, 1 of them a synthesis that pooled it.

0numbers the graph read from it
0cells of the map it votes in
33citing papers in PubMed, 1 pooled it
18.0field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

33 citing papers in PubMed, 1 synthesis or guideline pooled it, 265 citations in OpenAlex.

  1. Pooled it
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  9. Quantifying and characterizing major DOC fractions in water treatment processes: A simplified SPE method without recovering sorbed compounds.Water environment research : a research publication of the Water Environment Federation · 2025
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4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

C J NewcombPacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99354, USA.
N P QafokuPacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99354, USA.
J W GratePacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99354, USA.
V L BaileyPacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99354, USA.
J J De YoreoPacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99354, USA. james.deyoreo@pnnl.gov.
Pacific Northwest National Laboratory · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Long residence times of soil organic matter have been attributed to reactive mineral surface sites that sorb organic species and cause inaccessibility due to physical isolation and chemical stabilization at the organic-mineral interface. Instrumentation for probing this interface is limited. As a result, much of the micron- and molecular-scale knowledge about organic-mineral interactions remains largely qualitative. Here we report the use of force spectroscopy to directly measure the binding between organic ligands with known chemical functionalities and soil minerals in aqueous environments. By systematically studying the role of organic functional group chemistry with model minerals, we demonstrate that chemistry of both the organic ligand and mineral contribute to values of binding free energy and that changes in pH and ionic strength produce significant differences in binding energies. These direct measurements of molecular binding provide mechanistic insights into organo-mineral interactions, which could potentially inform land-carbon models that explicitly include mineral-bound C pools.Most molecular scale knowledge on soil organo-mineral interactions remains qualitative due to instrument limitations. Here, the authors use force spectroscopy to directly measure free binding energy between organic ligands and minerals and find that both chemistry and environmental conditions affect binding.

Identifiers

PMID28855506
PMCPMC5577185
OpenAlexW2750437866

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.