Evidence map›Paper›PMID 28838241›Full record

ArticleJournal of the American Chemical Society2017

Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki-Miyaura Coupling with Benzylic Esters: A Computational Study.

Shuo-Qing Zhang, Buck L H Taylor, Chong-Lei Ji, Yuan Gao, Michael R Harris, Luke E Hanna, Elizabeth R Jarvo, K N Houk, Xin Hong

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.

0numbers the graph read from it
0cells of the map it votes in
22citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

22 citing papers in PubMed.

  1. Article
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  8. Enantioselective Hydroalkoxylation of 1,3-Dienes via Ni-Catalysis.Journal of the American Chemical Society · 2023
    Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Harnessing C-O Bonds in Stereoselective Cross-Coupling and Cross-Electrophile Coupling Reactions.Synlett : accounts and rapid communications in synthetic organic chemistry · 2021
    Article
  15. Article
  16. Article
  17. Article
  18. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Shuo-Qing ZhangDepartment of Chemistry, Zhejiang University , Hangzhou 310027, China.
Buck L H TaylorDepartment of Chemistry and Biochemistry, University of California , Los Angeles, California 90095, United States.
Chong-Lei JiDepartment of Chemistry, Zhejiang University , Hangzhou 310027, China.
Yuan GaoDepartment of Chemistry, Zhejiang University , Hangzhou 310027, China.
Michael R HarrisDepartment of Chemistry, University of California , Irvine, California 92697, United States.
Luke E HannaDepartment of Chemistry, University of California , Irvine, California 92697, United States.
Elizabeth R JarvoDepartment of Chemistry, University of California , Irvine, California 92697, United States.
K N HoukDepartment of Chemistry and Biochemistry, University of California , Los Angeles, California 90095, United States.ORCID 0000-0002-8387-5261
Xin HongDepartment of Chemistry, Zhejiang University , Hangzhou 310027, China.ORCID 0000-0003-4717-2814

Funding

Stereospecific Nickel-Catalyzed Cross-Coupling for Pharmacophore SynthesisR01GM100212 · NIGMS · UNIVERSITY OF CALIFORNIA-IRVINE · PI JARVO, ELIZABETH REINHARDT · 2012 to 2016
$1.4M
Computational Investigation of Asymmetric Allylic Alkylation ReactionsF32GM106596 · NIGMS · UNIVERSITY OF CALIFORNIA LOS ANGELES · PI TAYLOR, BUCK · 2013 to 2015
$122k
NIGMS NIH HHS F32 GM106596NIGMS NIH HHS R01 GM100212
6 · The paper itself

Abstract

Nickel catalysts have shown unique ligand control of stereoselectivity in the Suzuki-Miyaura cross-coupling of boronates with benzylic pivalates and derivatives involving C(sp

Indexed as

Quantum TheoryBenzyl CompoundsCatalysisEstersLigandsMolecular StructureNickelStereoisomerismThermodynamicsBenzyl CompoundsEstersLigandsNickel

Identifiers

PMID28838241
PMCPMC5607113

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.