Evidence map›Paper›PMID 28836782›Full record

ArticleThe Journal of organic chemistry2017

Stabilization of 2,6-Diarylanilinum Cation by Through-Space Cation-π Interactions.

Joan Simó Padial, Jordi Poater, D Thao Nguyen, Paul Tinnemans, F Matthias Bickelhaupt, Jasmin Mecinović

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Quantifying Through-Space Substituent Effects.Angewandte Chemie (International ed. in English) · 2020
    Article
  5. Through-Space Polar-π Interactions in 2,6-Diarylthiophenols.Chemphyschem : a European journal of chemical physics and physical chemistry · 2020
    Article
  6. Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Joan Simó PadialInstitute for Molecules and Materials, Radboud University , Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.
Jordi PoaterCatalan Institution for Research and Advanced Studies (ICREA) , Passeig Lluís Companys 23, 08010 Barcelona, Spain.
D Thao NguyenInstitute for Molecules and Materials, Radboud University , Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.
Paul TinnemansInstitute for Molecules and Materials, Radboud University , Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.
F Matthias BickelhauptInstitute for Molecules and Materials, Radboud University , Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.ORCID 0000-0003-4655-7747
Jasmin MecinovićInstitute for Molecules and Materials, Radboud University , Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.ORCID 0000-0002-5559-3822

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Energetically favorable cation-π interactions play important roles in numerous molecular recognition processes in chemistry and biology. Herein, we present synergistic experimental and computational physical-organic chemistry studies on 2,6-diarylanilines that contain flanking meta/para-substituted aromatic rings adjacent to the central anilinium ion. A combination of measurements of pK

Identifiers

PMID28836782
PMCPMC5603827

What OpenQuestion holds

Textmetadata
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.