ArticleProceedings of the National Academy of Sciences of the United States of America2017
Mechanism of ion adsorption to aqueous interfaces: Graphene/water vs. air/water.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed, 107 citations in OpenAlex.
- When is nanoconfined water different from interfacial water?Faraday discussions · 2026Article
- How reactive is water at the nanoscale and how to control it?Science advances · 2026Article
- Breaking the Air-Water Paradigm: Ion Behavior at Hydrophobic Solid-Water Interfaces.Journal of the American Chemical Society · 2026Article
- It is Separation, Not Contact: Electrification at Water-Hydrophobe Interfaces during Wetting-Dewetting Cycles.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Electrostatic-driven dehydration of ions in nanoporous membranes.Science advances · 2025Article
- Spontaneous Surface Charging and Janus Nature of the Hexagonal Boron Nitride-Water Interface.Journal of the American Chemical Society · 2025Article
- Advanced characterization of confined electrochemical interfaces in electrochemical capacitors.Nature nanotechnology · 2025Review
- Why do some metal ions spontaneously form nanoparticles in water microdroplets? Disentangling the contributions of the air-water interface and bulk redox chemistry.Chemical science · 2025Article
- Transient Adsorption Behavior of Single Fluorophores on an Electrode-Supported Nanobubble.Chemical & biomedical imaging · 2023Article
- Simulations of Subnanometer Scale Image Contrast in Atomic Force Microscopy of Self-Assembled Monolayers in Water.Chemical & biomedical imaging · 2023Article
- Fluids and Electrolytes under Confinement in Single-Digit Nanopores.Chemical reviews · 2023Review
- Capturing charge and size effects of ions at the graphene-electrolyte interface using polarizable force field simulations.Nanoscale advances · 2023Article
- On the mechanisms of ion adsorption to aqueous interfaces: air-water vs. oil-water.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Influence of effective polarization on ion and water interactions within a biomimetic nanopore.Biophysical journal · 2022Article
- Weakly hydrated anions bind to polymers but not monomers in aqueous solutions.Nature chemistry · 2022Article
- Article
- Image-charge effects on ion adsorption near aqueous interfaces.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Assessing long-range contributions to the charge asymmetry of ion adsorption at the air-water interface.Chemical science · 2020Article
- Specific ion effects at graphitic interfaces.Nature communications · 2019Article
- Chemical physics of water.Proceedings of the National Academy of Sciences of the United States of America · 2017Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The adsorption of ions to aqueous interfaces is a phenomenon that profoundly influences vital processes in many areas of science, including biology, atmospheric chemistry, electrical energy storage, and water process engineering. Although classical electrostatics theory predicts that ions are repelled from water/hydrophobe (e.g., air/water) interfaces, both computer simulations and experiments have shown that chaotropic ions actually exhibit enhanced concentrations at the air/water interface. Although mechanistic pictures have been developed to explain this counterintuitive observation, their general applicability, particularly in the presence of material substrates, remains unclear. Here we investigate ion adsorption to the model interface formed by water and graphene. Deep UV second harmonic generation measurements of the SCN
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.