Evidence map›Paper›PMID 28824195›Full record

ArticleChemical physics letters2017

Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation.

Matthew C Patterson, Mark F DiTusa, Cheri A McFerrin, R L Kurtz, Randall W Hall, E D Poliakoff, P T Sprunger

Open access · greenAbstract read
In one paragraph

Article in Chemical physics letters, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers, 1 of them a synthesis that pooled it.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed, 1 pooled it
2.0field-weighted citation impact, top 16% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 1 synthesis or guideline pooled it, 55 citations in OpenAlex.

  1. Pooled it
  2. Article
  3. Role of Electronegativity in Environmentally Persistent Free Radicals (EPFRs) Formation on ZnO.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024
    Article
  4. Article
  5. Article
  6. Formation of Environmentally Persistent Free Radicals (EPFRs) on the Phenol-DosedThe journal of physical chemistry. C, Nanomaterials and interfaces · 2021
    Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 1 country.

Matthew C PattersonDepartment of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.
Mark F DiTusaDepartment of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803, USA.
Cheri A McFerrinDepartment of Natural Sciences and Mathematics, Dominican University of California, San Rafael, CA 94901, USA.
R L KurtzDepartment of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803, USA.
Randall W HallDepartment of Natural Sciences and Mathematics, Dominican University of California, San Rafael, CA 94901, USA.
E D PoliakoffDepartment of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.
P T SprungerDepartment of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803, USA.
Louisiana State University · USDominican University of California · US

Funding

Role of microbiota in increased influenza severity due to particulate matter exposureP42ES013648 · NIEHS · LOUISIANA STATE UNIV A&M COL BATON ROUGE · PI LOMNICKI, SLAWO M · 2009 to 2024
$27.6M
NIEHS NIH HHS P42 ES013648
6 · The paper itself

Abstract

Environmentally persistent free radicals (EPFRs) have significant environmental and public health impacts. In this study, we demonstrate that EPFRs formed on ZnO nanoparticles provide two significant surprises. First, EPR spectroscopy shows that phenoxy radicals form readily on ZnO nanoparticles at room temperature, yielding EPR signals similar to those previously measured after 250°C exposures. Vibrational spectroscopy supports the conclusion that phenoxy-derived species chemisorb to ZnO nanoparticles under both exposure temperatures. Second, DFT calculations indicate that electrons are transferred from ZnO to the adsorbed organic (oxidizing the Zn), the opposite direction proposed by previous descriptions of EPFR formation on metal oxides.

Identifiers

PMID28824195
PMCPMC5560487
OpenAlexW2561690787

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.