ArticleMolecules (Basel, Switzerland)2017
Copper-Catalyzed Synthesis of Unsymmetrical Diorganyl Chalcogenides (Te/Se/S) from Boronic Acids under Solvent-Free Conditions.
Article in Molecules (Basel, Switzerland), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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9 citing papers in PubMed.
- An Efficient Method for the Selective Syntheses of Sodium Telluride and Symmetrical Diorganyl Tellurides and the Investigation of Reaction Pathways.Molecules (Basel, Switzerland) · 2024Article
- Selenonium Salt as a Catalyst for Nucleophilic Substitution Reactions in Water: Synthesis of Thiocyanites and Selenocyanates.Molecules (Basel, Switzerland) · 2023Article
- "Green Is the Color": An Update on Ecofriendly Aspects of Organoselenium Chemistry.Molecules (Basel, Switzerland) · 2022Review
- Borophosphate glass as an active media for CuO nanoparticle growth: an efficient catalyst for selenylation of oxadiazoles and application in redox reactions.Scientific reports · 2020Article
- Selenylated-oxadiazoles as promising DNA intercalators: Synthesis, electronic structure, DNA interaction and cleavage.Dyes and pigments : an international journal · 2020Article
- A comparative study between Cu(INA)RSC advances · 2020Article
- Synthesis of Novel Selenocyanates and Evaluation of Their Effect in Cultured Mouse Neurons Submitted to Oxidative Stress.Oxidative medicine and cellular longevity · 2020Article
- Synthesis of 2,1,3-Benzoxadiazole Derivatives as New Fluorophores-Combined Experimental, Optical, Electro, and Theoretical Study.Frontiers in chemistry · 2020Article
- Celebrating Two Centuries of Research in Selenium Chemistry: State of the Art and New Prospective.Molecules (Basel, Switzerland) · 2017Article
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Abstract
The efficient and mild copper-catalyzed synthesis of unsymmetrical diorganyl chalcogenides under ligand- and solvent-free conditions is described. The cross-coupling reaction was performed using aryl boric acids and 0.5 equiv. of diorganyl dichalcogenides (Te/Se/S) in the presence of 3 mol % of CuI and 3 equiv. of DMSO, under microwave irradiation. This new protocol allowed the preparation of several unsymmetrical diorganyl chalcogenides in good to excellent yields.
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