ArticleEnvironmental science and pollution research international2017
Roles of polar groups and aromatic structures of biochar in 1-methyl-3-octylimidazolium chloride ionic liquid adsorption: pH effect and thermodynamics study.
Article in Environmental science and pollution research international, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Eco-friendly ionic liquid imprinted polymer based on a green synthesis strategy for highly selective adsorption tylosin in animal muscle samples.Environmental science and pollution research international · 2021Article
- Preparation of pickling-reheating activated alfalfa biochar with high adsorption efficiency for p-nitrophenol: characterization, adsorption behavior, and mechanism.Environmental science and pollution research international · 2019Article
- Characterization and 2D structural model of corn straw and poplar leaf biochars.Environmental science and pollution research international · 2018Article
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3 authors.
Funding
Abstract
Adsorption mechanisms of 1-methyl-3-octylimidazolium chloride ([OMIM]Cl) on rice straw-derived biochars produced at 400, 500, and 700 °C (referred as RB400, RB500, and RB700, respectively) were evaluated. Adsorption affinity followed the order of RB700 > RB400 > RB500. Electrostatic attraction and hydrogen bond controlled adsorption of [OMIM]Cl on RB400, while π-π EDA interaction between [OMIM]Cl and the aromatic rings of biochar dominated adsorption of RB500 and RB700. With increasing solution pH, -COOH and -OH on biochar became deprotonated. Consequently, [OMIM]Cl binding to these sites changed from hydrogen bond to electrostatic attraction. Adsorption capacity of [OMIM]Cl increased with increasing pH during the adsorption process. Solid concentration induced by -OH of [OMIM]Cl was higher than that of -COOH. Thermodynamics study indicated that adsorption process was spontaneous and endothermic. ∆H
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