ArticleAngewandte Chemie (International ed. in English)2017
Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed, 75 citations in OpenAlex.
- Cobaloxime-catalysed regiodivergent hydrogen atom transfer for alkenyl and allylic carbamoylation with branched alkenes.Nature communications · 2026Article
- Copper-Catalyzed Allylic Amination of Alkenes UsingACS catalysis · 2025Article
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- Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides.Nature communications · 2022Article
- Mitochondrial adaptation in cancer drug resistance: prevalence, mechanisms, and management.Journal of hematology & oncology · 2022Review
- Computational Design of Radical Recognition Assay with the Possible Application of Cyclopropyl Vinyl Sulfides as Tunable Sensors.International journal of molecular sciences · 2021Article
- Copper-Mediated Radical-Polar Crossover Enables Photocatalytic Oxidative Functionalization of Sterically Bulky Alkenes.Journal of the American Chemical Society · 2021Article
- Cu-catalyzed cyanomethylation of imines and α,β-alkenes with acetonitrile and its derivatives.RSC advances · 2021Article
- Intermolecular oxidative amination of unactivated alkenes by dual photoredox and copper catalysis.Chemical science · 2020Article
- Revealing the Iron-Catalyzed β-Methyl Scission ofMolecules (Basel, Switzerland) · 2020Article
- Cyanomethylation of Substituted Fluorenes and Oxindoles with Alkyl Nitriles.Organic letters · 2020Article
- Alkene Synthesis by Photocatalytic Chemoenzymatically Compatible Dehydrodecarboxylation of Carboxylic Acids and Biomass.ACS catalysis · 2019Article
- A new face of phenalenyl-based radicals in the transition metal-free C-H arylation of heteroarenes at room temperature: trapping the radical initiatorChemical science · 2017Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
We have developed a strategy to transform olefins into homoallylic nitriles through a mechanism that combines copper catalysis with alkyl nitrile radicals. The radicals are easily generated from alkyl nitriles in the presence of the mild oxidant di-tert-butyl peroxide. This cross-dehydrogenative coupling between simple olefins and alkylnitriles bears advantages over the conventional use of halides and toxic cyanide reagents. With this method, we showcase the facile synthesis of a flavoring agent, a natural product, and a polymer precursor from simple olefins.
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