ArticleAngewandte Chemie (International ed. in English)2017
Self-Regulated and Temporal Control of a "Breathing" Microgel Mediated by Enzymatic Reaction.
Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
22 citing papers in PubMed.
- Kinetically Controlled and Nonequilibrium Assembly of Block Copolymers in Solution.Journal of the American Chemical Society · 2024Review
- Dampened Transient Actuation of Hydrogels Autonomously Controlled by pH-Responsive Bicontinuous Nanospheres.ACS applied materials & interfaces · 2024Article
- A transient vesicular glue for amplification and temporal regulation of biocatalytic reaction networks.Chemical science · 2023Article
- Nonlinear Transient Permeability in pH-Responsive Bicontinuous Nanospheres.Journal of the American Chemical Society · 2023Article
- Photoswitchable gating of non-equilibrium enzymatic feedback in chemically communicating polymersome nanoreactors.Nature chemistry · 2023Article
- Biocatalytic cascades and intercommunicated biocatalytic cascades in microcapsule systems.Chemical science · 2022Article
- Dissipative biocatalytic cascades and gated transient biocatalytic cascades driven by nucleic acid networks.Science advances · 2022Article
- Dissipative operation of pH-responsive DNA-based nanodevices.Chemical science · 2021Article
- pH Feedback Lifecycles Programmed by Enzymatic Logic Gates Using Common Foods as Fuels.Angewandte Chemie (International ed. in English) · 2021Article
- Time-programmable pH: decarboxylation of nitroacetic acid allows the time-controlled rising of pH to a definite value.Chemical science · 2021Article
- Performing calculus: Asymmetric adaptive stimuli-responsive material for derivative control.Science advances · 2021Article
- Bioinspired Networks of Communicating Synthetic Protocells.Frontiers in molecular biosciences · 2021Review
- Four-Dimensional Deoxyribonucleic Acid-Gold Nanoparticle Assemblies.Angewandte Chemie (International ed. in English) · 2020Article
- ATP-fuelled self-assembly to regulate chemical reactivity in the time domain.Chemical science · 2019Article
- Adaptive Polymeric Assemblies for Applications in Biomimicry and Nanomedicine.Biomacromolecules · 2019Article
- ATP-Mediated Transient Behavior of Stomatocyte Nanosystems.Angewandte Chemie (International ed. in English) · 2019Review
- Bio-inspired temporal regulation of ion-transport in nanochannels.Nanoscale advances · 2019Article
- Shear-induced assembly of a transient yet highly stretchable hydrogel based on pseudopolyrotaxanes.Nature chemistry · 2019Article
- Immobilization adjusted clock reaction in the urea-urease-HRSC advances · 2019Article
- Bioinspired temporal supramolecular polymerization.RSC advances · 2018Review
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Naturally occurring systems have the ability to self-regulate, which plays a key role in their structural and functional adaptation. The autonomous behavior in living systems is biocatalytically controlled by the continuous consumption of energy to remain in a non-equilibrium condition. In this work, we show the construction of a self-regulated "breathing" microgel that uses chemical fuels to keep the system in the out-of-equilibrium state. The enzyme urease is utilized to program a feedback-induced pH change, which in turn tunes the size switch and fluorescence intensity of the microgel. A continuous supply of chemical fuels to the system allows the process to be reversible. This microgel with tunable autonomous properties provides insights into the design of artificial systems and dynamic soft materials.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.