Evidence map›Paper›PMID 28766325›Full record

ArticleAngewandte Chemie (International ed. in English)2017

C-H Activation from Iron(II)-Nitroxido Complexes.

Claudia Kleinlein, Andrew J Bendelsmith, Shao-Liang Zheng, Theodore A Betley

Open access · greenAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
0.7field-weighted citation impact, top 31% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 19 citations in OpenAlex.

  1. Manipulating Terminal Iron-Hydroxide Nucleophilicity through Redox.Journal of the American Chemical Society · 2026
    Article
  2. Article
  3. Article
  4. Article
  5. Dioxygen-Derived Nonheme Mononuclear FeJournal of the American Chemical Society · 2019
    Article
  6. Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2018
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Claudia KleinleinDepartment of Chemistry & Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.
Andrew J BendelsmithDepartment of Chemistry & Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.
Shao-Liang ZhengDepartment of Chemistry & Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.
Theodore A BetleyDepartment of Chemistry & Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.ORCID 0000-0001-5946-9629
Harvard University · US

Funding

Correlation of electronic structure to iron catalyzed C-H bond functionalizationR01GM115815 · NIGMS · HARVARD UNIVERSITY · PI BETLEY, THEODORE A · 2015 to 2018
$1.3M
NIGMS NIH HHS R01 GM115815
6 · The paper itself

Abstract

The reaction of nitroxyl radicals TEMPO (2,2',6,6'-tetramethylpiperidinyloxyl) and AZADO (2-azaadamantane-N-oxyl) with an iron(I) synthon affords iron(II)-nitroxido complexes (

Indexed as

AdamantaneCarbonCrystallography, X-RayCyclic N-OxidesFerrous CompoundsHydrogenLigandsMacromolecular SubstancesNitrogen OxidesSpectrophotometry, InfraredSpectroscopy, Mossbauer2-azaadamantane N-oxylAdamantaneCarbonCyclic N-OxidesFerrous CompoundsHydrogenLigandsMacromolecular SubstancesNitrogen OxidesTEMPOC−H activationdipyrrin ligandhydrogen atom abstractioniron complexesnitroxyl radical

Identifiers

PMID28766325
PMCPMC5672810
OpenAlexW2742049577

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.