ArticleJournal of the American Chemical Society2017
Redox Control over Acyl Hydrazone Photoswitches.
Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Dynamic Control of Nucleic Acids Self-Assembly and Expression Using Photoswitches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Emergent Behavior of a Photoswitchable Solute in a Biphasic Solvent System.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- All-visible-light-driven salicylidene schiff-base-functionalized artificial molecular motors.Nature communications · 2024Article
- Fully Reversible and Super-Fast Photo-Induced Morphological Transformation of Nanofilms for High-Performance UV Detection and Light-Driven Actuators.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- A new series of acylhydrazones derived from metribuzin with modulated herbicidal activity.Heliyon · 2023Article
- Isomerization of bioactive acylhydrazones triggered by light or thiols.Nature chemistry · 2023Article
- Catalyst- and Additive-Free C(spACS omega · 2022Article
- Acylhydrazone-based supramolecular assemblies undergoing a converse sol-to-gel transition onChemical science · 2022Article
- Monitoring the photochemistry of a formazan over 15 orders of magnitude in time.Frontiers in chemistry · 2022Article
- Molecular photoswitches in aqueous environments.Chemical Society reviews · 2021Review
- Trace mild acid-catalysedChemical science · 2020Article
- Article
- Fabrication of Photoresponsive Crystalline Artificial Muscles Based on PEGylated Covalent Organic Framework Membranes.ACS central science · 2020Article
- Photodynamic Control of the Chain Length in Supramolecular Polymers: Switching an Intercalator into a Chain Capper.Journal of the American Chemical Society · 2020Article
- Straightforward synthesis of gold nanoparticles by adding water to an engineered small dendrimer.Beilstein journal of nanotechnology · 2020Article
- Article
- Multiple adaptation of constitutional dynamic networks and information storage in constitutional distributions of acylhydrazones.Chemical science · 2019Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photoisomerization provides a clean and efficient way of reversibly altering physical properties of chemical systems and injecting energy into them. These effects have been applied in development of systems such as photoresponsive materials, molecular motors, and photoactivated drugs. Typically, switching from more to less stable isomer(s) is performed by irradiation with UV or visible light, while the reverse process proceeds thermally or by irradiation using another wavelength. In this work we developed a method of rapid and tunable Z→E isomerization of C═N bond in acyl hydrazones, using aromatic thiols as nucleophilic catalysts. As thiols can be oxidized into catalytically inactive disulfides, the isomerization rates can be controlled via the oxidation state of the catalyst, which, together with the UV irradiation, provides orthogonal means to control the E/Z state of the system. As a proof of this concept, we have applied this method to control the diversity of acyl hydrazone based dynamic combinatorial libraries.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.