ReviewChemical Society reviews2017
Cycloaddition reactions of enoldiazo compounds.
Review in Chemical Society reviews, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
28 citing papers in PubMed.
- Bromination Functionalization of Diazo Compounds with CBrOrganic letters · 2026Article
- Asymmetric formal [1 + 2 + 2]-cycloaddition of diazoamides with enamines and carbonyl compounds.Nature communications · 2025Article
- Iron-Catalyzed Intermolecular N-H Insertion Using Acceptor-Acceptor Carbenes Derived from Iodonium Ylides.Organic letters · 2025Article
- Photolytic Access to Oxaspirodecanes and Chromenes from Vinyldiazo Ester Cycloaddition withJournal of the American Chemical Society · 2025Article
- Asymmetric multi-component trifunctionalization reactions with α-Halo Rh-carbenes.Nature communications · 2025Article
- Visible Light-Induced Reactions of Diazo Compounds and Their Precursors.Chemical reviews · 2024Review
- Photo-cycloaddition reactions of vinyldiazo compounds.Nature communications · 2024Article
- The "cesium effect" magnified: exceptional chemoselectivity in cesium ion mediated nucleophilic reactions.Chemical science · 2024Article
- Nickel(II)-Catalyzed Formal [3+2] Cycloadditions between Indoles and Donor-Acceptor Cyclopropanes.Molecules (Basel, Switzerland) · 2024Article
- Photocatalytic Boryl Radicals Triggered Sequential B─N/C─N Bond Formation to Assemble Boron-Handled Pyrazoles.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- B(COrganic letters · 2023Article
- Organic transformations in the confined space of porous organic cage CC2; catalysis or inhibition.RSC advances · 2022Article
- Visible Light Induced Brønsted Acid Assisted Pd-Catalyzed Alkyl Heck Reaction of Diazo Compounds and N-Tosylhydrazones.Angewandte Chemie (International ed. in English) · 2022Article
- Stereoselective Synthesis of Tri- and Tetrasubstituted Olefins via 1,6-Additions of Diazo Compounds and Their Precursors toACS organic & inorganic Au · 2021Article
- Copper-catalyzed asymmetric cyclization of alkenyl diynes: method development and new mechanistic insights.Chemical science · 2021Article
- Diazocarbonyl and Related Compounds in the Synthesis of Azoles.Molecules (Basel, Switzerland) · 2021Review
- Formal [4 + 4]-, [4 + 3]-, and [4 + 2]-cycloaddition reactions of donor-acceptor cyclobutenes, cyclopropenes and siloxyalkynes induced by Brønsted acid catalysis.Chemical science · 2021Article
- Regio- and Diastereoselective Dimerization of Diazo Carbonyls: A Cooperative Catalytic Approach to Complex Scaffolds with Four Contiguous Stereocenters.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Triarylborane-Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds.Angewandte Chemie (International ed. in English) · 2020Article
- Visible light-induced photocatalytic C-H ethoxycarbonylmethylation of imidazoheterocycles with ethyl diazoacetate.RSC advances · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition reactions that allow highly efficient construction of various carbocycles and heterocycles. Their versatility is exemplified by (1) [2+n]-cycloadditions (n = 3, 4) by the enol silyl ether units of enoldiazo compounds with retention of the diazo functionality to furnish α-cyclic-α-diazo compounds that are themselves subject to further transformations of the diazo functional group; (2) [3+n]-cycloadditions (n = 1-5) by metallo-enolcarbenes formed by catalytic dinitrogen extrusion from enoldiazo compounds; (3) [2+n]-cycloadditions (n = 3, 4) by donor-acceptor cyclopropenes generated in situ from enoldiazo compounds that produce cyclopropane-fused ring systems. The role of dirhodium(ii) and the emergence of copper(i) catalysts are described, as are the different outcomes of reactions initiated with these catalysts. This comprehensive review on cycloaddition reactions of enoldiazo compounds, with emphasis on methodology development, mechanistic insight, and catalyst-controlled chemodivergence, aims to provide inspiration for future discoveries in the field and to catalyze the application of enoldiazo reagents by the wider synthetic community.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.