Evidence map›Paper›PMID 28706638›Full record

ArticleChemical science2015

Non-equilibrium cobalt(iii) "click" capsules.

P R Symmers, M J Burke, D P August, P I T Thomson, G S Nichol, M R Warren, C J Campbell, P J Lusby

Abstract read
In one paragraph

Article in Chemical science, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
  4. Self-Assembled Tetrahedral [CrInorganic chemistry · 2024
    Article
  5. Review
  6. Article
  7. Double-Bridging Increases the Stability of Zinc(II) Metal-Organic Cages.Journal of the American Chemical Society · 2024
    Article
  8. CageCavityCalc (Journal of chemical information and modeling · 2024
    Article
  9. Article
  10. Review
  11. Article
  12. Host Spin-Crossover Thermodynamics Indicate Guest Fit.Angewandte Chemie (International ed. in English) · 2022
    Article
  13. Article
  14. Article
  15. Cavity-Containing [FeFrontiers in chemistry · 2021
    Article
  16. Article
  17. Article
  18. Article
  19. Oxidatively Locked [Co₂L₃]Molecules (Basel, Switzerland) · 2016
    Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

P R SymmersEaStCHEM School of Chemistry , University of Edinburgh , The King's Buildings, David Brewster Road , Edinburgh EH9 3FJ , UK . Email: Paul.Lusby@ed.ac.uk.
M J BurkeEaStCHEM School of Chemistry , University of Edinburgh , The King's Buildings, David Brewster Road , Edinburgh EH9 3FJ , UK . Email: Paul.Lusby@ed.ac.uk.
D P AugustEaStCHEM School of Chemistry , University of Edinburgh , The King's Buildings, David Brewster Road , Edinburgh EH9 3FJ , UK . Email: Paul.Lusby@ed.ac.uk.
P I T ThomsonEaStCHEM School of Chemistry , University of Edinburgh , The King's Buildings, David Brewster Road , Edinburgh EH9 3FJ , UK . Email: Paul.Lusby@ed.ac.uk.
G S NicholEaStCHEM School of Chemistry , University of Edinburgh , The King's Buildings, David Brewster Road , Edinburgh EH9 3FJ , UK . Email: Paul.Lusby@ed.ac.uk.
M R WarrenDiamond Light Source Ltd , Diamond House, Harwell Science and Innovation Campus, Didcot , Oxfordshire OX11 0DE , UK.
C J CampbellEaStCHEM School of Chemistry , University of Edinburgh , The King's Buildings, David Brewster Road , Edinburgh EH9 3FJ , UK . Email: Paul.Lusby@ed.ac.uk.
P J LusbyEaStCHEM School of Chemistry , University of Edinburgh , The King's Buildings, David Brewster Road , Edinburgh EH9 3FJ , UK . Email: Paul.Lusby@ed.ac.uk.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Cobalt(iii) tetrahedral capsules have been prepared using an assembly-followed-by-oxidation protocol from a cobalt(ii) precursor and a readily derivatizable pyridyl-triazole ligand system. Experiments designed to probe the constitutional dynamics show that these architectures are in a non-equilibrium state. A preliminary investigation into the host-guest chemistry of a water-soluble derivative shows it can bind and differentiate a range of different neutral organic molecules. The stability of this ensemble also permits the study of guest-binding at high salt concentrations.

Identifiers

PMID28706638
PMCPMC5494537

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.