ArticleJournal of the American Chemical Society2017
Cobalt Catalysis for Enantioselective Cyclobutanone Construction.
Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Construction of remote dual stereocenters by electrochemical cobalt-catalyzed enantioselective desymmetrization.Nature communications · 2026Article
- Stereospecific Synthesis of Cyclobutanones and Spirohexanones via Formal [3 + 1] Cycloaddition of Cyclopropanones with Sulfur Ylides.Organic letters · 2025Article
- Pathway-divergent coupling of alkynes and cyclobutenes through enantioselective cobalt catalysis.Nature communications · 2025Article
- Data-driven design of new chiral carboxylic acid for construction of indoles with C-central and C-N axial chirality via cobalt catalysis.Nature communications · 2023Article
- Activator-free single-component Co(I)-catalysts for regio- and enantioselective heterodimerization and hydroacylation reactions of 1,3-dienes. New reduction procedures for synthesis of [L]Co(I)-complexes and comparison toDalton transactions (Cambridge, England : 2003) · 2022Article
- Cobalt-N-Heterocyclic Carbene Complexes in Catalysis.ACS catalysis · 2022Article
- Catalytic asymmetric hydrometallation of cyclobutenes with salicylaldehydes.Chemical science · 2021Article
- A New Paradigm in Enantioselective Cobalt Catalysis: Cationic Cobalt(I) Catalysts for Heterodimerization, Cycloaddition, and Hydrofunctionalization Reactions of Olefins.Accounts of chemical research · 2021Article
- A catalytic asymmetric cross-coupling approach to the synthesis of cyclobutanes.Nature chemistry · 2021Article
- α- and β-Functionalized Ketones from 1,3-Dienes and Aldehydes: Control of Regio- and Enantioselectivity in Hydroacylation of 1,3-Dienes.Journal of the American Chemical Society · 2021Article
- New Catalytic Radical Process Involving 1,4-Hydrogen Atom Abstraction: Asymmetric Construction of Cyclobutanones.Journal of the American Chemical Society · 2021Article
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- Enantioselective Hydrothiolation: Diverging Cyclopropenes through Ligand Control.Journal of the American Chemical Society · 2021Article
- Teaching Aldehydes New Tricks Using Rhodium- and Cobalt-Hydride Catalysis.Accounts of chemical research · 2021Review
- Ligand Substitution and Electronic Structure Studies of Bis(phosphine)Cobalt Cyclooctadiene Precatalysts for Alkene Hydrogenation.Canadian journal of chemistry · 2021Article
- Catalytic Enantioselective Synthesis of Cyclobutenes from Alkynes and Alkenyl Derivatives.Journal of the American Chemical Society · 2019Article
- Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications.Journal of the American Chemical Society · 2019Article
- Tandem catalysis for asymmetric coupling of ethylene and enynes to functionalized cyclobutanes.Science (New York, N.Y.) · 2018Article
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Authors and funding
4 authors.
Funding
Abstract
Over the past 40 years, intramolecular hydroacylation has favored five-membered rings, in preference to four membered rings. Herein, we report a catalyst derived from earth-abundant cobalt that enables preparation of cyclobutanones, with excellent regio-, diastereo-, and enantiocontrol, under mild conditions (2 mol % catalyst loading and as low as 50 °C).
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.