ArticleChemical science2017
Halogen bonded Borromean networks by design: topology invariance and metric tuning in a library of multi-component systems.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed, 45 citations in OpenAlex.
- Taxonomy of Chemical Bondings: Opportunities and Challenges.Angewandte Chemie (International ed. in English) · 2025Article
- Integrating Full-Color 2D Optical Waveguide and Heterojunction Engineering in Halide Microsheets for Multichannel Photonic Logical Gates.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Comparison of N···I and N···O Halogen Bonds in Organoiodine Cocrystals of Heterocyclic Aromatic Diazine Mono-Crystal growth & design · 2024Article
- Principles and Applications of CFJournal of medicinal chemistry · 2023Review
- Stacking Interactions: A Supramolecular Approach to Upgrade Weak Halogen Bond Donors.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Predictability of Chalcogen-Bond-Driven Crystal Engineering: An X-ray Diffraction and Selenium-77 Solid-State NMR Investigation of Benzylic Selenocyanate Cocrystals.ACS organic & inorganic Au · 2022Article
- Stimuli Responsive Materials Supported by Orthogonal Hydrogen and Halogen Bonding or I···Alkene Interaction.Molecules (Basel, Switzerland) · 2021Article
- Halogen bonding as a supramolecular dynamics catalyst.Nature communications · 2019Article
- Connectivity and Topology Invariance in Self-Assembled and Halogen-Bonded Anionic (6,3)-Networks.Molecules (Basel, Switzerland) · 2017Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 4 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A library of supramolecular anionic networks showing Borromean interpenetration has been prepared by self-assembly of crypt-222, several metal or ammonium halides, and five bis-homologous α,ω-diiodoperfluoroalkanes. Halogen bonding has driven the formation of these anionic networks. Borromean entanglement has been obtained starting from all the four used cations, all the three used anions, but only two of the five used diiodoperfluoroalkanes. As the change of the diiodoperfluoroalkane, the cation, or the anion has a different relative effect on the metrics and bondings of the self-assembled systems, it can be generalized that bonding, namely energetic, features play here a less influential role than metric features in determining the topology of the prepared tetra-component cocrystals. This conclusion may hold true for other multi-component systems and may function as a general heuristic principle when pursuing the preparation of multi-component systems having the same topology but different composition.
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Registered trials
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