Evidence map›Paper›PMID 28686205›Full record

ArticleMolecules (Basel, Switzerland)2017

Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation.

Kohei Matsuzaki, Tomoya Hiromora, Hideki Amii, Norio Shibata

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Molecules (Basel, Switzerland), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
1.0field-weighted citation impact, top 29% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 23 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 1 country.

Kohei MatsuzakiDepartment of Nanopharmaceutical Sciences, Nagoya Institute of Technology Gokiso, Showa-ku, Nagoya 466-8555, Japan. cht11134@nitech.jp.
Tomoya HiromoraDepartment of Life Science and Applied Chemistry, Nagoya Institute of Technology Gokiso, Showa-ku, Nagoya 466-8555, Japan.
Hideki AmiiDivision of Molecular Science, Graduate School of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan. 28411141@stn.nitech.ac.jp.
Norio ShibataDepartment of Nanopharmaceutical Sciences, Nagoya Institute of Technology Gokiso, Showa-ku, Nagoya 466-8555, Japan. nozshiba@nitech.ac.jp.
Nagoya Institute of Technology · JPGunma University · JP

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We disclose herein the perfluoroalkylation of alkenes catalyzed by trifluoroethoxy-coated zinc phthalocyanine under irradiation of visible light. Perfluoroalkyl iodides were nicely incorporated into unsaturated substrates, including alkyne, to provide perfluoroalkyl and iodide adducts in moderate to good yields. Trifluoromethylation is also possible by trifluoromethyl iodide under the same reaction conditions. The mechanistic study is discussed.

Indexed as

AlkenesAlkylationAlkynesCatalysisHydrocarbons, FluorinatedIndolesIodidesIsoindolesLightMagnetic Resonance SpectroscopyMolecular StructureOrganometallic CompoundsZinc CompoundsAlkenesAlkynesHydrocarbons, FluorinatedIndolesIodidesIsoindolesOrganometallic CompoundsZinc CompoundsZn(II)-phthalocyanineperfluoroalkylationphotocatalystsphthalocyaninetrifluoromethylationvisible light

Identifiers

PMID28686205
PMCPMC6152348
OpenAlexW2732065586

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.