ArticleChemistry (Weinheim an der Bergstrasse, Germany)2017
Nitrene Radical Intermediates in Catalytic Synthesis.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 66 papers.
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66 citing papers in PubMed.
- Photochemical Cascade Nitrile Activation via a Carbene-Nitrene Relay.Angewandte Chemie (International ed. in English) · 2026Article
- Reaction Pathway and Axial Ligand Effects of C(spJACS Au · 2026Article
- Photoactive Iminobismuthanes for Catalytic C-H Amination.Journal of the American Chemical Society · 2026Article
- Photo-induced selective N-N bond construction via harnessing nitrene release and transfer.Nature communications · 2026Article
- A Series of Trigonal Arylimido Iron Complexes and the Influence of Oxidation State and Steric Demand on Reactivity.Inorganic chemistry · 2025Article
- Nitrogen Subvalency in a Four-Member Redox Series of Iron-Sulfur Cluster Imido Complexes.Journal of the American Chemical Society · 2025Article
- Mechanistic Insights into the Reductive N-O Bond Cleavage ofACS organic & inorganic Au · 2025Article
- Tip-Induced Nitrene Generation.ACS nano · 2025Article
- An Iron-Catalyzed Sustainable Functional Group Transfer Strategy for In-Water Transformation of Organic Sulfides to Sulfoxides by a Hydroxylamine-Derived Oxidant.ChemSusChem · 2025Article
- Photogeneration and Visualization of a Surface-Stabilized Dinitrene.Angewandte Chemie (International ed. in English) · 2025Article
- Nitrene-mediated glycosylation with thioglycoside donors under metal catalysis.Science advances · 2025Article
- P-P CouplingJournal of the American Chemical Society · 2025Article
- Article
- A Mechanistic Study on Iron-Based Styrene Aziridination: Understanding Epoxidation via Nitrene Hydrolysis.Molecules (Basel, Switzerland) · 2024Article
- HowJACS Au · 2023Article
- Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an UnusualJournal of the American Chemical Society · 2023Article
- Catalytic, asymmetric carbon-nitrogen bond formation using metal nitrenoids: from metal-ligand complexesChemical science · 2023Review
- Article
- Homotropic Cooperativity in Iron-Catalyzed Alkyne Cyclotrimerizations.ACS catalysis · 2023Article
- Poly(glycidyl azide) as Photo-Crosslinker for Polymers.Polymers · 2022Article
6 more citing papers are in PubMed but not listed here.
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4 authors.
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Abstract
Nitrene radical complexes are reactive intermediates with discrete spin density at the nitrogen-atom of the nitrene moiety. These species have become important intermediates for organic synthesis, being invoked in a broad range of C-H functionalization and aziridination reactions. Nitrene radical complexes have intriguing electronic structures, and are best described as one-electron reduced Fischer type nitrenes. They can be generated by intramolecular single electron transfer to the "redox non-innocent" nitrene moiety at the metal. Nitrene radicals generated at open-shell cobalt(II) have thus far received most attention in terms of spectroscopic characterization, reactivity screening, catalytic nitrene-transfer reactions and (computational and experimental) mechanistic studies, but some interesting iron and precious metal catalysts have also been employed in related reactions involving nitrene radicals. In some cases, redox-active ligands are used to facilitate intramolecular single electron transfer from the complex to the nitrene moiety. Organic azides are among the most attractive nitrene precursors in this field, typically requiring pre-activated organic azides (e.g. RSO
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