Evidence map›Paper›PMID 28671470›Full record

ArticleJournal of the American Chemical Society2017

Separating Proton and Electron Transfer Effects in Three-Component Concerted Proton-Coupled Electron Transfer Reactions.

Wesley D Morris, James M Mayer

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.

0numbers the graph read from it
0cells of the map it votes in
35citing papers in PubMed
3.2field-weighted citation impact, top 7% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

35 citing papers in PubMed, 97 citations in OpenAlex.

  1. Mapping Proton-Coupled Electron Transfer With Real Space Coordinates.Angewandte Chemie (International ed. in English) · 2026
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  5. Revisiting H‑BondACS omega · 2025
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  14. Chemo- and Site-Selective Electro-Oxidative Alkane Fluorination by C(spChemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
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  16. Article
  17. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors at 1 institution in 1 country.

Wesley D MorrisDepartment of Chemistry, Yale University , New Haven, Connecticut 06511, United States.
James M MayerDepartment of Chemistry, Yale University , New Haven, Connecticut 06511, United States.ORCID 0000-0002-3943-5250
Yale University · US

Funding

UNDERSTANDING METAL MEDIATED C-H AND O-H BOND OXIDATIONSR01GM050422 · NIGMS · YALE UNIVERSITY · PI MAYER, JAMES M · 1995 to 2020
$6.1M
NIGMS NIH HHS R01 GM050422
6 · The paper itself

Abstract

Multiple-site concerted proton-electron transfer (MS-CPET) reactions were studied in a three-component system. 1-Hydroxy-2,2,6,6-tetramethylpiperidine (TEMPOH) was oxidized to the stable radical TEMPO by electron transfer to ferrocenium oxidants coupled to proton transfer to various pyridine bases. These MS-CPET reactions contrast with the usual reactivity of TEMPOH by hydrogen atom transfer (HAT) to a single e

Indexed as

ElectronsProtonsElectron TransportHydrogen BondingKineticsMolecular StructureOxidation-ReductionPiperidinesThermodynamics2,2,6,6-tetramethylpiperididePiperidinesProtons

Identifiers

PMID28671470
PMCPMC5812448
OpenAlexW2729104732

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.