ArticleACS photonics2017
Light-Directed Tuning of Plasmon Resonances via Plasmon-Induced Polymerization Using Hot Electrons.
Article in ACS photonics, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Automated Plasmon-Selective Laser Writing in Mesoporous Thin Films Through Decoupling of the Initiator Absorption and Plasmon Wavelength.Small science · 2026Article
- Printed photonic crystal biochips for rapid and sensitive detection of biomarkers in various body fluids.Nature protocols · 2025Review
- Sensing Thermophoretic Forces by Nanoplasmonic Actuators with Interferometric Scattering Readout.Nano letters · 2025Article
- Condensed Matter Systems Exposed to Radiation: Multiscale Theory, Simulations, and Experiment.Chemical reviews · 2024Review
- Plasmonic Effect of Gold-Patchy Silica Nanoparticles on Green Light-Photopolymerizable Dental Resin.Nanomaterials (Basel, Switzerland) · 2023Article
- Article
- The Effect of Femtosecond Laser Irradiation and Plasmon Field on the Degree of Conversion of a UDMA-TEGDMA Copolymer Nanocomposite Doped with Gold Nanorods.International journal of molecular sciences · 2022Article
- Responsive photonic nanopixels with hybrid scatterers.Nanophotonics (Berlin, Germany) · 2022Review
- Microscopic Understanding of Reaction Rates Observed in Plasmon Chemistry of Nanoparticle-Ligand Systems.The journal of physical chemistry. C, Nanomaterials and interfaces · 2022Article
- Light-Mediated Polymerization Induced by Semiconducting Nanomaterials: State-of-the-Art and Future Perspectives.ACS polymers Au · 2021Review
- In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111).Nature communications · 2021Article
- New Variants of Nitroxide Mediated Polymerization.Polymers · 2020Review
- Extreme nanophotonics from ultrathin metallic gaps.Nature materials · 2019Review
- Terahertz-driven polymerization of resists in nanoantennas.Scientific reports · 2018Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The precise morphology of nanoscale gaps between noble-metal nanostructures controls their resonant wavelengths. Here we show photocatalytic plasmon-induced polymerization can locally enlarge the gap size and tune the plasmon resonances. We demonstrate light-directed programmable tuning of plasmons can be self-limiting. Selective control of polymer growth around individual plasmonic nanoparticles is achieved, with simultaneous real-time monitoring of the polymerization process in situ using dark-field spectroscopy. Even without initiators present, we show light-triggered chain growth of various monomers, implying plasmon initiation of free radicals via hot-electron transfer to monomers at the Au surface. This concept not only provides a programmable way to fine-tune plasmons for many applications but also provides a window on polymer chemistry at the sub-nanoscale.
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Registered trials
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