ArticleChemical communications (Cambridge, England)2017
Integrative self-sorting of coordination cages based on 'naked' metal ions.
Article in Chemical communications (Cambridge, England), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 59 papers.
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Who cites it
59 citing papers in PubMed, 215 citations in OpenAlex.
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- Low Symmetry Cage Complexes Formed by Metalation of Symmetric Hexa-Cationic Organic Cages.Angewandte Chemie (International ed. in English) · 2025Article
- Coordination sphere interactions drive isomer selection in heteroleptic Pd(ii) cages with low-symmetry ligands.Chemical science · 2025Article
- Topological variety and self-sorting in homo- and heteroleptic PdChemical science · 2025Review
- Concentration Gradient-Induced Syntheses and Crystal Structures of Two Copper(II) Coordination Polymer Based on Phthalic Acid and 2,2'-Bipyridine.Molecules (Basel, Switzerland) · 2025Article
- Intricate Low-Symmetry AgJournal of the American Chemical Society · 2024Article
- Structural Transformations of Metal-Organic Cages through Tetrazine-Alkene Reactivity.Journal of the American Chemical Society · 2024Article
- Formation of a low-symmetry PdChemical science · 2024Article
- A pair of conjoined trinuclear sub-frameworks in a pentanuclear double-cavity discrete coordination cage.Chemical science · 2024Article
- Triamine and Tetramine Edge-Length Matching Drives Heteroleptic Triangular and Tetragonal Prism Assembly.Journal of the American Chemical Society · 2024Article
- Assembly of Six Types of Heteroleptic PdJournal of the American Chemical Society · 2023Article
- Diastereoselective Self-Assembly of Low-Symmetry PdAngewandte Chemie (International ed. in English) · 2023Article
- PdChemical science · 2023Article
- Engineering Soluble Diketopyrrolopyrrole Chromophore Stacks from a Series of Pd(II)-Based Ravels.Angewandte Chemie (International ed. in English) · 2023Article
- Phototriggered structures: Latest advances in biomedical applications.Acta pharmaceutica Sinica. B · 2023Review
- Aqueous Three-Component Self-Assembly of a Pseudo[1]rotaxane Using Hydrazone Bonds.The Journal of organic chemistry · 2023Article
- Secondary Bracing Ligands Drive Heteroleptic Cuboctahedral PdJournal of the American Chemical Society · 2023Article
- Exposing Mechanisms for Defect Clearance in Supramolecular Self-Assembly: Palladium-Pyridine Coordination Revisited.Inorganic chemistry · 2023Article
- Stepwise assembly of heterometallic, heteroleptic "triblock Janus-type" metal-organic polyhedra.Chemical communications (Cambridge, England) · 2023Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Coordination-driven self-assembly of metal ions and organic ligands has been extensively utilised over the past four decades to access a variety of nano-sized cage assemblies, with functions ranging from sensing and catalysis to drug delivery. Many of the reported examples, however, are highly symmetric architectures that contain one type of organic ligand carrying not more than a single functionality. This contrasts significantly with the level of structural and functional complexity encountered in biological macromolecular hosts, which are able to bind and chemically convert smaller molecules in their highly-decorated internal cavities. To address this disparity, rational approaches that facilitate heteroleptic assembly by regulating integrative self-sorting of metal ions and multiple ligand components have emerged. Among these, routes to access coordination cages from 'naked' metal cations that offer more than two coordination sites are still in early development, as the complexity of the self-sorted products in terms of composition and stereochemistry presents an entropic challenge. This feature article highlights recent progress in controlling integrative self-sorting of multi-component cage systems with a focus on structures composed of 'naked' metal cations and two different ligands. Once heteroleptic self-assembly strategies find a wider implementation in supramolecular design, the resultant interplay between tailored combinations of precisely positioned substituents promises enhanced functionality in nanoscale structures.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.