ArticleChemistry (Weinheim an der Bergstrasse, Germany)2017
Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 63 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
63 citing papers in PubMed.
- Chiral Macrocycle-Enabled In-Situ Trapping of Catalytically Active Peroxometalate Anions for Directing Asymmetric Sulfoxidation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Eco-friendly synthesis of silver nanoparticles as an unexplored application of photoredox catalysis.Nanoscale advances · 2026Article
- Photochemical reduction of aryl chlorides, bromides, and iodidesChemical science · 2026Article
- Phenazine-Based Homogeneous Photocatalysts for Visible-Light-Driven Hydrogenation of Nitroarenes Under Mild Conditions.Molecules (Basel, Switzerland) · 2026Article
- Expanding Thermodynamic and Kinetic Frontiers in Molecular Photocatalysis.ACS central science · 2026Review
- Indole Photocatalysts and Secondary Amine Ligands Enable Nickel-Photoredox C(spACS catalysis · 2025Article
- Transfer learning across different photocatalytic organic reactions.Nature communications · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- New Opportunities to Access Fluorinated Molecules Using Organophotoredox Catalysis via C(spJACS Au · 2025Review
- Photocatalytic systems: reactions, mechanism, and applications.RSC advances · 2024Review
- Mechanisms of Photoredox Catalysis Featuring Nickel-Bipyridine Complexes.ACS catalysis · 2024Review
- Mechanistic investigations of polyaza[7]helicene in photoredox and energy transfer catalysis.Beilstein journal of organic chemistry · 2024Article
- Characterization of the Reversible Intersystem Crossing Dynamics of Organic Photocatalysts Using Transient Absorption Spectroscopy and Time-Resolved Fluorescence Spectroscopy.The journal of physical chemistry. A · 2023Article
- Impact of Alkyl Core Substitution Kinetics in Diaryl Dihydrophenazine Photoredox Catalysts on Properties and Performance in O-ATRP.ACS catalysis · 2023Article
- Riboflavin and Eosin Y Supported on Chromatographic Silica Gel as Heterogeneous Photocatalysts.ACS omega · 2023Article
- Ru(phen)ChemistryOpen · 2023Article
- Article
- Alternatives to Iridium: A Polyaza[7]helicene as a Strongly Reductive Visible Light Photoredox Catalyst.ACS organic & inorganic Au · 2022Article
- The Nickel Age in Synthetic Dual Photocatalysis: A Bright Trip Toward Materials Science.ChemSusChem · 2022Review
- Direct C-H Trifluoromethylation of (Hetero)Arenes in Water Enabled by Organic Photoredox-Active Amphiphilic Nanoparticles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
3 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors.
Funding
Abstract
Photoredox catalysis is a versatile approach for the construction of challenging covalent bonds under mild reaction conditions, commonly using photoredox catalysts (PCs) derived from precious metals. As such, there is need to develop organic analogues as sustainable replacements. Although several organic PCs have been introduced, there remains a lack of strongly reducing, visible-light organic PCs. Herein, we establish the critical photophysical and electrochemical characteristics of both a dihydrophenazine and a phenoxazine system that enables their success as strongly reducing, visible-light PCs for trifluoromethylation reactions and dual photoredox/nickel-catalyzed C-N and C-S cross-coupling reactions, both of which have been historically exclusive to precious metal PCs.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.