ArticleNature chemistry2017
Observation of electron-transfer-mediated decay in aqueous solution.
Article in Nature chemistry, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
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Who cites it
13 citing papers in PubMed.
- Imaging quantum chemistry in action with quantum attomicroscopy.Communications chemistry · 2026Review
- Tracking the Complex Dynamics of Electron-Transfer-Mediated Decay in Real Space and Time.Journal of the American Chemical Society · 2026Article
- Electron Transfer and Negative Ion Formation.The journal of physical chemistry letters · 2025Review
- The OÆSE endstation at BESSY II: operando X-ray absorption spectroscopy for energy materials.Journal of synchrotron radiation · 2025Article
- The solvation shell probed by resonant intermolecular Coulombic decay.Nature communications · 2024Article
- X-ray radiation damage cycle of solvated inorganic ions.Nature communications · 2024Article
- Radiation damage by extensive local water ionization from two-step electron-transfer-mediated decay of solvated ions.Nature chemistry · 2023Article
- Triple ionization and fragmentation of benzene trimers following ultrafast intermolecular Coulombic decay.Nature communications · 2022Article
- Probing aqueous ions with non-local Auger relaxation.Physical chemistry chemical physics : PCCP · 2022Article
- Signature of the neighbor's quantum nuclear dynamics in the electron transfer mediated decay spectra.Chemical science · 2021Article
- Interatomic and Intermolecular Coulombic Decay.Chemical reviews · 2020Article
- Heavy NNature communications · 2020Article
- Do water's electrons care about electrolytes?Chemical science · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photoionization is at the heart of X-ray photoelectron spectroscopy (XPS), which gives access to important information on a sample's local chemical environment. Local and non-local electronic decay after photoionization-in which the refilling of core holes results in electron emission from either the initially ionized species or a neighbour, respectively-have been well studied. However, electron-transfer-mediated decay (ETMD), which involves the refilling of a core hole by an electron from a neighbouring species, has not yet been observed in condensed phase. Here we report the experimental observation of ETMD in an aqueous LiCl solution by detecting characteristic secondary low-energy electrons using liquid-microjet soft XPS. Experimental results are interpreted using molecular dynamics and high-level ab initio calculations. We show that both solvent molecules and counterions participate in the ETMD processes, and different ion associations have distinctive spectral fingerprints. Furthermore, ETMD spectra are sensitive to coordination numbers, ion-solvent distances and solvent arrangement.
Identifiers
28644468What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.