Evidence map›Paper›PMID 28613847›Full record

ArticleJournal of the American Chemical Society2017

Type II Anion Relay Chemistry: Conformational Constraints To Achieve Effective [1,5]-Vinyl Brook Rearrangements.

Qi Liu, Yu Chen, Xiao Zhang, K N Houk, Yong Liang, Amos B Smith

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Total Synthesis of (-)-Nahuoic Acid CJournal of the American Chemical Society · 2017
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Qi LiuDepartment of Chemistry, University of Pennsylvania , Philadelphia, Pennsylvania 19104, United States.
Yu ChenState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210023, China.
Xiao ZhangState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210023, China.
K N HoukDepartment of Chemistry and Biochemistry, University of California , Los Angeles, California 90095, United States.ORCID 0000-0002-8387-5261
Yong LiangState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210023, China.ORCID 0000-0001-5026-6710
Amos B SmithDepartment of Chemistry, University of Pennsylvania , Philadelphia, Pennsylvania 19104, United States.ORCID 0000-0002-1712-8567

Funding

SYNTHESIS OF PHYLLANTHOSIDE RELATED ANTITUMOR AGENTSR01CA019033 · NCI · UNIVERSITY OF PENNSYLVANIA · PI SMITH, AMOS B · 1985 to 2024
$5.9M
THE MILBEMYCINS: POTENT ANTHELMINTIC AGENTSR01GM029028 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI SMITH, AMOS B · 1985 to 2015
$4.0M
NCI NIH HHS R01 CA019033NIGMS NIH HHS R01 GM029028
6 · The paper itself

Abstract

The design, synthesis, and evaluation of bifunctional linchpins, conformationally anchored on six-membered rings to achieve efficient [1,5]-Brook rearrangements involving vinyl silanes have been achieved. The restrained linchpins were subsequently exploited in type II anion relay chemistry (ARC) to permit both alkylations and Pd-mediated cross-coupling reactions (CCR) of sp

Indexed as

AnionsCopperMolecular ConformationSilanesVinyl CompoundsAnionsCopperSilanesVinyl Compounds

Identifiers

PMID28613847
PMCPMC5558205

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.