ArticleChemistry (Weinheim an der Bergstrasse, Germany)2017
Gold Redox Catalysis through Base-Initiated Diazonium Decomposition toward Alkene, Alkyne, and Allene Activation.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Synergistic Action of Ascorbic Acid and Readily Accessible NHC^N Ligands for the Oxidation of Gold(I) With Electron-Rich Aryldiazonium Salts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- An Enantioselective Alkene Aminoarylation to Form Chiral Indolines via Electrostatically-Directed Palladium Catalysis.Angewandte Chemie (International ed. in English) · 2026Article
- Oxidant-free Au(I)/Au(III) catalysis: Rational development of hemilabile proximity-guided N-heterocyclic carbenes.Science advances · 2026Article
- Accessing gold p-acid reactivity under electrochemical anode oxidation (EAO) through oxidation relay.Nature communications · 2023Article
- Accessing Gold π-Acid Reactivity under Electrochemical Anode Oxidation (EAO) through Oxidation Relay.Research square · 2023Article
- Stereoselective Total Synthesis of (-)-Thallusin for Bioactivity Profiling.Angewandte Chemie (International ed. in English) · 2022Article
- Hemilabile MIC^N ligands allow oxidant-free Au(i)/Au(iii) arylation-lactonization of γ-alkenoic acids.Chemical science · 2022Article
- Reactant-induced photoactivation of in situ generated organogold intermediates leading to alkynylated indoles via CspNature communications · 2022Article
- Alkyne Trifunctionalization via Divergent Gold Catalysis: Combining π-Acid Activation, Vinyl-Gold Addition, and Redox Catalysis.Journal of the American Chemical Society · 2021Article
- Electrochemical gold redox catalysis for selective oxidative arylation.Green synthesis and catalysis · 2021Article
- Homogeneous Gold Redox Chemistry: Organometallics, Catalysis, and Beyond.Trends in chemistry · 2020Article
- Hexafluoroisopropanol-Promoted Disulfidation and Diselenation of Alkyne, Alkene, and Allene.Organic letters · 2020Article
- Diazo Activation with Diazonium Salts: Synthesis of Indazole and 1,2,4-Triazole.Organic letters · 2020Article
- Base-Promoted Radical Azofluoromethylation of Unactivated Alkenes.Organic letters · 2020Article
- Light-Induced Mechanistic Divergence in Gold(I) Catalysis: Revisiting the Reactivity of Diazonium Salts.Angewandte Chemie (International ed. in English) · 2019Review
- Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles.Chemical science · 2019Article
- Gold redox catalysis for cyclization/arylation of allylic oximes: synthesis of isoxazoline derivatives.Chemical communications (Cambridge, England) · 2019Article
- Highly Efficient and Stereoselective Thioallylation of Alkynes: Possible Gold Redox Catalysis with No Need for a Strong Oxidant.Angewandte Chemie (International ed. in English) · 2018Article
- Iodine-catalyzed diazo activation to access radical reactivity.Nature communications · 2018Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
The discovery of photoassisted diazonium activation toward gold(I) oxidation greatly extended the scope of gold redox catalysis by avoiding the use of a strong oxidant. Some practical issues that limit the application of this new type of chemistry are the relative low efficiency (long reaction time and low conversion) and the strict reaction condition control that is necessary (degassing and inert reaction environment). Herein, an alternative photofree condition has been developed through Lewis base induced diazonium activation. With this method, an unreactive Au
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