ArticleThe journal of physical chemistry letters2017
Steering Self-Assembly of Amphiphilic Molecular Nanostructures via Halogen Exchange.
Article in The journal of physical chemistry letters, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Light-Induced Selective Control of Excitonic States in Supramolecular Nanotubes.Journal of the American Chemical Society · 2026Article
- Disordered light-harvesting aggregates can host functional vibronic couplings at room temperature.Nature communications · 2026Article
- Near-atomic-resolution structure of J-aggregated helical light-harvesting nanotubes.Nature chemistry · 2024Article
- Watching Molecular Nanotubes Self-Assemble in Real Time.Journal of the American Chemical Society · 2023Article
- Manifestation of Hydrogen Bonding and Exciton Delocalization on the Absorption and Two-Dimensional Electronic Spectra of Chlorosomes.The journal of physical chemistry. B · 2023Article
- Modelling structural properties of cyanine dye nanotubes at coarse-grained level.Nanoscale advances · 2022Article
- Cryogenic TEM imaging of artificial light harvesting complexes outside equilibrium.Scientific reports · 2022Article
- The role of chirality and plastic crystallinity in the optical and mechanical properties of chlorosomes.iScience · 2022Article
- Molecular versus Excitonic Disorder in Individual Artificial Light-Harvesting Systems.Journal of the American Chemical Society · 2020Article
- Multiscale modeling of molecular structure and optical properties of complex supramolecular aggregates.Chemical science · 2020Article
- Stereochemistry-Controlled Supramolecular Architectures of New Tetrahydroxy-Functionalised Amphiphilic Carbocyanine Dyes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Interplay between structural hierarchy and exciton diffusion in artificial light harvesting.Nature communications · 2019Article
- Molecular model of J-aggregated pseudoisocyanine fibers.The Journal of chemical physics · 2018Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In the field of self-assembly, the quest for gaining control over the supramolecular architecture without affecting the functionality of the individual molecular building blocks is intrinsically challenging. By using a combination of synthetic chemistry, cryogenic transmission electron microscopy, optical absorption measurements, and exciton theory, we demonstrate that halogen exchange in carbocyanine dye molecules allows for fine-tuning the diameter of the self-assembled nanotubes formed by these molecules, while hardly affecting the molecular packing determined by hydrophobic/hydrophilic interactions. Our findings open a unique way to study size effects on the optical properties and exciton dynamics of self-assembled systems under well-controlled conditions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.