Evidence map›Paper›PMID 28580109›Full record

ArticleChemical science2017

Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis-Hillman reaction.

Alberto Martinez-Cuezva, Adrian Saura-Sanmartin, Tomas Nicolas-Garcia, Cristian Navarro, Raul-Angel Orenes, Mateo Alajarin, Jose Berna

Abstract read
In one paragraph

Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.

0numbers the graph read from it
0cells of the map it votes in
26citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

26 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Article
  5. Photoswitchable Catalysis by a Self-Assembled Molecular Cage.Journal of the American Chemical Society · 2024
    Article
  6. Article
  7. Article
  8. Artificial molecular machines: Design and observation.Smart molecules : open access · 2023
    Review
  9. Article
  10. Article
  11. Article
  12. Article
  13. Review
  14. Review
  15. Review
  16. Article
  17. Article
  18. Functional Rotaxanes in Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Review
  19. Review
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Alberto Martinez-CuezvaDepartamento de Química Orgánica , Facultad de Química , Regional Campus of International Excellence "Campus Mare Nostrum" , Universidad de Murcia , E-30100 , Murcia , Spain . Email: ppberna@um.es.ORCID 0000-0001-8093-7888
Adrian Saura-SanmartinDepartamento de Química Orgánica , Facultad de Química , Regional Campus of International Excellence "Campus Mare Nostrum" , Universidad de Murcia , E-30100 , Murcia , Spain . Email: ppberna@um.es.
Tomas Nicolas-GarciaDepartamento de Química Orgánica , Facultad de Química , Regional Campus of International Excellence "Campus Mare Nostrum" , Universidad de Murcia , E-30100 , Murcia , Spain . Email: ppberna@um.es.
Cristian NavarroDepartamento de Química Orgánica , Facultad de Química , Regional Campus of International Excellence "Campus Mare Nostrum" , Universidad de Murcia , E-30100 , Murcia , Spain . Email: ppberna@um.es.
Raul-Angel OrenesSAI , Universidad de Murcia , E-30100 , Murcia , Spain.
Mateo AlajarinDepartamento de Química Orgánica , Facultad de Química , Regional Campus of International Excellence "Campus Mare Nostrum" , Universidad de Murcia , E-30100 , Murcia , Spain . Email: ppberna@um.es.ORCID 0000-0002-7112-5578
Jose BernaDepartamento de Química Orgánica , Facultad de Química , Regional Campus of International Excellence "Campus Mare Nostrum" , Universidad de Murcia , E-30100 , Murcia , Spain . Email: ppberna@um.es.ORCID 0000-0001-7775-3703

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

En route to a photoswitchable interlocked catalyst we have proved the ability of thiodiglycolamide to act as a template in the formation of hydrogen-bonded [2]rotaxanes. X-ray diffraction studies reveal the shielding of the sulfide atom by the macrocycle. A series of molecular shuttles are described as having an isomerizable fumaramide and thiodiglycolamide binding sites for controlling the relative ring position at will. By employing these systems as photoregulated catalysts, the TiCl

Identifiers

PMID28580109
PMCPMC5436546

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.