ArticleChemical science2017
Copper(i)-catalyzed sulfonylative Suzuki-Miyaura cross-coupling.
Article in Chemical science, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Beyond traditional defunctionalized cross-coupling reaction: scope, limitations, practicability & future prospects of recent electrochemical methodologies.RSC advances · 2026Review
- Carbonylative Aminative Suzuki-Miyaura Coupling: Pd-Catalyzed Synthesis of Amides from Vinyl/Aryl Halides and Boronic Acids.Journal of the American Chemical Society · 2026Article
- Advances in sulfonyl exchange chemical biology: expanding druggable target space.Chemical science · 2025Review
- Direct Synthesis of Benzhydryl-Functionalized 3,4-Dihydropyridin-2-ones from 2-Pyridones and Their Use in the Formation of Bridged δ-Lactams.Molecules (Basel, Switzerland) · 2024Article
- An efficient and mild oxidative approach from thiols to sulfonyl derivatives with DMSO/HBr.Chemical science · 2023Article
- Recent Advances of S-ACS omega · 2023Review
- Experimental and computational insights into the mechanism of the copper(i)-catalysed sulfonylative Suzuki-Miyaura reaction.Chemical science · 2023Article
- Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides.Tetrahedron · 2023Article
- Photocatalytic Sulfonyl Fluorination of Alkyl Organoboron Substrates.ACS catalysis · 2023Article
- Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SOAngewandte Chemie (International ed. in English) · 2022Article
- Tricomponent Decarboxysulfonylative Cross-Coupling Facilitates Direct Construction of Aryl Sulfones and Reveals a Mechanistic Dualism in the Acridine/Copper Photocatalytic System.ACS catalysis · 2022Article
- Amine-Catalyzed Copper-Mediated C-H Sulfonylation of Benzaldehydes via a Transient Imine Directing Group.Angewandte Chemie (International ed. in English) · 2022Article
- (Hetero)aryl-SAngewandte Chemie (International ed. in English) · 2022Review
- Sulfonyl fluorides as targets and substrates in the development of new synthetic methods.Nature reviews. Chemistry · 2022Review
- Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides.Journal of the American Chemical Society · 2021Article
- Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.ChemSusChem · 2021Review
- Rediscovering Sulfinylamines as Reagents for Organic Synthesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Divergent reactivity of sulfinates with pyridinium salts based on one-Chemical science · 2021Article
- Site-Selective C-H Functionalization-Sulfination Sequence to Access Aryl Sulfonamides.Organic letters · 2020Article
- Cyclic Alkenylsulfonyl Fluorides: Palladium-Catalyzed Synthesis and Functionalization of Compact Multifunctional Reagents.Angewandte Chemie (International ed. in English) · 2019Article
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Authors and funding
2 authors.
Funding
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Abstract
Using a simple copper(i) catalyst has allowed a high yielding sulfonylative-Suzuki-Miyaura cross-coupling reaction to be developed. The process provides a single step route to diaryl sulfones from the direct combination of aryl boronic acids, sulfur dioxide and aryl iodides, and represents the first sulfonylative variant of a classic cross-coupling reaction. Sulfur dioxide is delivered from the surrogate reagent, DABSO. Variation of the reaction conditions allowed interruption of the sulfonylative-Suzuki coupling, resulting in the formation of a presumed Cu-sulfinate intermediate. These sulfinates could be trapped as their sodium salts and treated with electrophiles to allow access to arylalkyl sulfones, β-hydroxyl sulfones, sulfonamides and sulfonyl fluorides.
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Registered trials
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